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2nd Law of thermodynamics | Spontaneity ...

2nd Law of thermodynamics | Spontaneity of a reaction | Gibbs free energy

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I. Read the following passage and answer questions 1-5 that follows: Spontaneity means the feasibility of a reaction.Gibbs free energy (G) is the thermodynamic quantity which helps in predicting the spontaneity of a process G = H - TS The change in free energy is represented by Gibbs Helmoltz equation, DeltaH - DeltaH - TDeltaS For spontaneity of a process, DeltaG must be negative.It depends upon energy factor (DeltaH) and entropy factor (TDeltaS) . 1. What are the signs of DeltaH and DeltaS for the reactions : 2CI(g) to CI_(2)(g) ?

Assertion (A): The thermodynamic factor which determines the spontaneity of a process is the free energy. For a process to be spontaneous the free energy must be-ve. Reason (R ) : The change in free energy is related to the change in a process must always be positive if its is spontaneous.

According to the second law of thermodynamics, a process (reaction) is spontaneous, if during the process

Statement: The thermodynamics functions which determines the spontaneity of a process is the free energy. For a process to be spontaneous, the change in free energy must be negative. Explanation:The change in free energy is related to the change in enthalpy and change in entropy. the change in entropy for a process must be always positive if it is spontaneous.

Applications of relation between gibbs free energy and EMF

Which of the following can help to predict the rate of reaction if the standard Gibb's free energy of reaction (Delta_rG^@) is known ?

The transfer of energy from one trophic level to another is governed by the 2nd law of thermodynamics. The average efficiency of energy transfer from herbivores to carnivores is

Variation of enthalpy and entropy of reaction with Temperature || Gibbs function || Condition for spontaneity || Physical significance of Gibbs free energy