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A isomerism to B on addition of traces o...


A isomerism to B on addition of traces of acid `H_(2)SO_(4)`. Compound (B) is:

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A isomerise to B on addition of traces of acid H_2 SO_4 . Compound (B) is :

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An compound (A) which undergo halogorm reaction give compound (B) on reduction . Compound (B) on dehydration with conc. H_(2)SO_(4) gives compound ( C ) which forms secondary butylbromide with HBr. Identify (A).

Ethanoic acid + 3 methyl-1-butanol underset("traces" H_(2)SO_(4))hArr (A) , Compound (A) is :

Black solid underset(Delta)overset(KOH+Air)to underset(("green"))((A))overset(H_(2)SO_(4))to underset(("purple"))((B))+(C) (i) KI on reaction with alkali solution of (B) changes into a compound (D). (ii) The colour of the compound (B) disappears on treatment with the acidic solution of FeSO_(4) (iii) With cold conc. H_(2)SO_(4) compound (B) gives (E), which being explosive decomposes to yield (F) and oxygen. ltBrgt Q. Type of hybridization in compound (D) is:

Black solid underset(Delta)overset(KOH+Air)to underset(("green"))((A))overset(H_(2)SO_(4))to underset(("purple"))((B))+(C) (i) KI on reaction with alkali solution of (B) changes into a compound (D). (ii) The colour of the compound (B) disappears on treatment with the acidic solution of FeSO_(4) (iii) With cold conc. H_(2)SO_(4) compound (B) gives (E), which being explosive decomposes to yield (F) and oxygen. ltBrgt Q. Type of hybridization in compound (D) is: