Home
Class 11
CHEMISTRY
If K(1),K(2),K(3) are equilibrium consta...

If `K_(1),K_(2),K_(3)` are equilibrium constant for formation of `AD,AD_(2),AD_(3)` respectively as follows `A+DhArrD,AD+DhArrAD_(2),AD_(2)+DhArrAD_(3)`. Then equilibrium constant `'K' "for" A+3DhArrAD_(3)` is related as

A

`K_(1)+K_(2)+K_(3)=K`

B

`logK_(1)+logK_(2)+logK_(3)=logK`

C

`K_(1)+K_(2)=K_(3)+K`

D

`logK_(1)+logK_(2)=logK_(3)+logK`

Text Solution

Verified by Experts

The correct Answer is:
B

`A+dhArrAD,K_(1)`
`AD+DhArrAD_(2),K_(2)`
`(AD_(2)+DhArrAD_(3),K_(3))/(A+3DhArrAD_(3),K)`
As we know that `K=K_(1).K_(2).K_(3)`
Or, `logK=logK_(1)+logK_(2)+logK_(3)`
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL EQUILIBRIUM

    RESONANCE|Exercise Exercise-2 (Part-2)|23 Videos
  • CHEMICAL EQUILIBRIUM

    RESONANCE|Exercise Exercise-2 (Part-3)|34 Videos
  • CHEMICAL EQUILIBRIUM

    RESONANCE|Exercise Exercise-1 (Part-2)|88 Videos
  • CHEMICAL BONDING

    RESONANCE|Exercise Inorganic chemistry (Chemistry Bonding)|49 Videos
  • D & F-BLOCK ELEMENTS & THEIR IMPORTANT COMPOUNDS

    RESONANCE|Exercise Match the column|1 Videos

Similar Questions

Explore conceptually related problems

The equilibrium constant for the reversible reaction N_(2)+3H_(2) hArr 2NH_(3) is K and for the reaction (1)/(2) N_(2)+(3)/(2) H_(2) hArr NH_(3) , the equilibrium constant is K',.K and K' will be related as

For the hypothetic reaction, the equilibrium constant (K) values are given A hArr B,K_(1)=2.0 B hArr C, K_(2)=4.0 ChArr D, K_(3) =3.0 The equilibrium constant for the reaction A hArr D is

For the hypothetical reactions, the equilibrium constant (K) value are given AhArrB,K_(1)=2,BhArrC,K_(2)=4, ChArrD,K_(3)=3 The equilibrium constant (K) for the reaction AhArrD is

The equilibrium constant for the reactions N_(2)+O_(2)hArr2NO"and "NO+1/2O_(2)hArrNO_(2)"are"K_(1)"and"K_(2) respectively, that will be the equilibrium constant for the reaction

consider the following gaseous equilibrium with equilibrium constant K_(1) and K_(2) respectively SO_(2)(g)+ 1//2O_(2)hArrSO_(3)(g) 2SO_(3)(g)hArr2SO_(2)(g)+O_(2)(g) The equilibrium constants are related as

In alkaline solution, the following equilibria exist a. S^(2-)+S rarr S_(2)^(2-) equilibrium constant K_(1) b. S_(2)^(2-)+S rarr S_(3)^(2-) equilibrium constant K_(2) K_(1) and K_(2) have values 12 and 11 , respectively. S_(3)^(2-) rarr S^(2-)+2S . What is equilibrium constant for the reaction

The equilibrium constants for the reactions are H_3PO_(4) overset(K_1)( H_2PO_(4) overset(K_2)( HPO_(4)^(2-) overset(K_2)( The equilibrium constant for H_3PO_4

RESONANCE-CHEMICAL EQUILIBRIUM-Exercise-2 (Part-1)
  1. The equilibrium constant (K(p)) for the reaction, PCl(5(g))hArrPCl(3(g...

    Text Solution

    |

  2. If K(1),K(2),K(3) are equilibrium constant for formation of AD,AD(2),A...

    Text Solution

    |

  3. In the reaction, N(2)+O(2)hArr2NO, the moles//litre of N(2),O(2) "and"...

    Text Solution

    |

  4. The reaction, PCI(5)hArrPCI(3)+CI(2) is started in a five litre contai...

    Text Solution

    |

  5. a' moles of PCI(5), undergoes, thermal dissociation as: PCI(5)hArrPCI(...

    Text Solution

    |

  6. For the following gases equilibrium, N(2)O(4)(g)hArr2NO(2)(g) K(p) i...

    Text Solution

    |

  7. Sulphide ions in alkaline solution react with solid sulphur to form po...

    Text Solution

    |

  8. For which of the reaction, the ratio (K(P))/(K(C)) is maximum and mini...

    Text Solution

    |

  9. If for 2A(2)B(g)hArr2A(2)(g)+B(2)(g),K(P)="TOTAL PRESSURE" ("at equili...

    Text Solution

    |

  10. Ammonia gas at 15 atm is introduced in a rigid vessel at 300 K. At equ...

    Text Solution

    |

  11. Attainment of the equilibrium A(g)hArr2C(g)+B(g)gave the following gra...

    Text Solution

    |

  12. A 10 L "container at" 300K "contains" CO(2) "gas at pressure of" 0.2 "...

    Text Solution

    |

  13. Two solid A "and" B are present in two different container having same...

    Text Solution

    |

  14. In the system, LaCI(3(s)) + H(2)O(g) rarr LaCIO(s) + 2HCI(g) - heat ...

    Text Solution

    |

  15. Some quantity of water is contained in a container as shown in figure....

    Text Solution

    |

  16. The equilibrium constant for, 2H(2)S(g)hArr2H(2)(g)+S(2)(g) "is" 0.011...

    Text Solution

    |

  17. For reaction, assuming large volume of water. H(2)O(l)hArrH(2)O(g) ,...

    Text Solution

    |

  18. Na(2)SO(4).10H(2)O(s)hArrNa(2)SO(4).5H(2)O(g) K(P)=2.43xx10^(-10) atm^...

    Text Solution

    |

  19. For equilibrium ZnSO(4).7H(2)O(s)hArrZnSO(4).2H(2)O(s)+5H(2)O(g) K(P...

    Text Solution

    |

  20. In the Haber process for the industrial manufacturing of ammonia invol...

    Text Solution

    |