Home
Class 11
CHEMISTRY
Variation of log(10)K with (1)/(T) is sh...

Variation of `log_(10)K` with `(1)/(T)` is shown by the following graph in which straight line is at `45^(@)` , hence `Delta H^(@)` is:

A

`+4.606cal`

B

`-4.606cal`

C

`2cal`

D

`-2cal`

Text Solution

Verified by Experts

The correct Answer is:
B

`K=Ae^(-DeltaH//RT)`
`logK=logA-(DeltaH)/(2.303RT)`.
`log K=logA-(DeltaH)/(2.303R)xx(1)/(T)`.
`log K=[-(DeltaH)/(2.303R)]xx(1)/(T)+logA`.
(-DeltaH)/(2.303R)=1`. ltbgt `DeltaH=-2.303R=-4.606cal`.
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL EQUILIBRIUM

    RESONANCE|Exercise Advanced Level Problems (Part-2)(Section-2)|7 Videos
  • CHEMICAL EQUILIBRIUM

    RESONANCE|Exercise Advanced Level Problems (Part-2)(Section-3)|6 Videos
  • CHEMICAL EQUILIBRIUM

    RESONANCE|Exercise Advanced Level Problems (Part-1)|31 Videos
  • CHEMICAL BONDING

    RESONANCE|Exercise Inorganic chemistry (Chemistry Bonding)|49 Videos
  • D & F-BLOCK ELEMENTS & THEIR IMPORTANT COMPOUNDS

    RESONANCE|Exercise Match the column|1 Videos

Similar Questions

Explore conceptually related problems

Which of the following graph yield a straight line?

In S.H.M. which one of the following graphs is a straight line ?

Which of the following graphs is not a straight line for an ideal gas ?

Write equations for the straight lines shown in the following graphs.

In SHM, graph of which of the following is a straight line?

The graph between log k versus 1//T is a straight line.

Variation of K_(H) (Henry's law constant )with temperature T is shown by following graphs I-IV correct representaion is

If a plant of log_(10) C versust t gives a straight line for a given reaction, then the reaction is :