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Reaction between benzaldehyde and acetop...

Reaction between benzaldehyde and acetophenone in presence of dilute NaOH is known as:

A

Aldol condensation

B

Cannizzaro's reaction

C

Cross Cannizzaro's reaction

D

Cross Aldol condensation

Text Solution

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The correct Answer is:
To determine the type of reaction that occurs between benzaldehyde and acetophenone in the presence of dilute NaOH, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - Benzaldehyde (C6H5CHO) is an aldehyde. - Acetophenone (C6H5COCH3) is a ketone. 2. **Understand the Reaction Conditions**: - The reaction occurs in the presence of dilute NaOH, which is a basic medium. This indicates that we are likely dealing with a reaction that involves deprotonation and nucleophilic attack. 3. **Determine the Presence of Alpha Hydrogens**: - Aldol reactions require at least one alpha hydrogen on the carbon adjacent to the carbonyl group. - Benzaldehyde has no alpha hydrogens (the carbon adjacent to the carbonyl is part of the aromatic ring). - Acetophenone has three alpha hydrogens (the methyl group adjacent to the carbonyl group). 4. **Identify the Type of Reaction**: - Since benzaldehyde lacks alpha hydrogens, it cannot undergo aldol condensation by itself. However, acetophenone can undergo aldol condensation due to the presence of alpha hydrogens. - When benzaldehyde and acetophenone react together, they undergo a cross aldol condensation reaction. 5. **Conclusion**: - The reaction between benzaldehyde and acetophenone in the presence of dilute NaOH is known as **cross aldol condensation**.
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The intermediate(s) involved perkin condensation between benzaldehyde and acetic anhydride in the presence of sodium acetate is/are.

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Knowledge Check

  • Reaction between benzaldehyde and acetophenone in presence of dilute NaOH is kown as :

    A
    Cannizzaro's reaction
    B
    Cross Cannizzaro's reaction
    C
    Cross Aldol condensation
    D
    Aldol condensation
  • The reaction between phenol and chloroform in the presence of aqueous NaOH is

    A
    nucleophilic substitution reaction
    B
    electrophilic addition reaction
    C
    electrophilic substitution reaction
    D
    nucleophilic addition reaction.
  • When a mixture of benzaldehyde and acetophenone is treated with dilute NaOH at 293 K , it form

    A
    2, 3-diphenylpropanal
    B
    1, 1-diphenylpropan-2-one-1-ol
    C
    1, 3-diphenylprop-2-en-1-one
    D
    1, 2-diphenylprop-2-en-1-one
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    (A) Friedel-Crafts reaction between benzene and acetic angydride in presence of anhydrous AICI_(3) yields acetophenone and not polysubstitution product. ( R) Acetophenone formed poisons the catalyst, preventing further reaction.