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Transition metals usually from coloured ...

Transition metals usually from coloured complexes and d-d transitions `(t_(2g)hArre_(g))` are responsible for colour as the energy difference between `t_(2g)` and `e_(g)` lies in visible region. But all the coloured ions are not dut to d-d transition but charge transfer bands also play important roles. Charge transfer bands may be of two types.
(i) ligand to metal (CTLM)`" "(ii)` metal to ligand (CTML).
Charge transfer transition always produces intense colour as compared to d-d transition.
Select the incorrect statement `:`

A

d-block metal ions are usually coloured.

B

colour of the most of d-block metal ions is enerally due to d-d transiton.

C

All the complexes of `Cu^(+)` are colourless on account of diamagnetic nature i.e., `d^(10)` configuration

D

`CrO_(3)` is bright orange due to CTLM.

Text Solution

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The correct Answer is:
C
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Transition metals usually from coloured complexes and d-d transitions (t_(2g)hArre_(g)) are responsible for colour as the energy difference between t_(2g) and e_(g) lies in visible region. But all the coloured ions are not dut to d-d transition but charge transfer bands also play important roles. Charge transfer bands may be of two types. (i) ligand to metal (CTLM) " "(ii) metal to ligand (CTML). Charge transfer transition always produces intense colour as compared to d-d transition. MnO_(4)^(-) is dark purple coloured though Mn is in (+VII) oxidation state with 3d^(@) configuration

Which is coloured because of d-d transition ?

In which of the following ions, the colour is not due to d-d transition?

Transition metals are coloured due to the following electronic transition

In which of the following transition metal ion complexes, the colour in not due to d-d transition?

RESONANCE-D & F-BLOCK ELEMENTS & THEIR IMPORTANT COMPOUNDS -Exercise 2
  1. Transition elements have greater tendency to form complexes because th...

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  2. Which of the following statements are correct?

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  3. The melting point of Zn is lower as compared to those of the other ele...

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  4. The less stable oxidation states of Cr are:

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  5. Which of the following statement is/are correct?

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  6. Select correct statement(s).

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  7. The colour of the transition metal ions is due to

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  8. Which of the following chemical reaction(s) is//are involved in develo...

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  9. Which of the following statement are correct when a mixture of NaCl a...

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  10. Which of the following statement(s) is/are correct?

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  11. Pyrolusite is MnO(2) used to prepare KMnO(4). Steps are, MnO(2)overset...

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  12. Which of the following statements are correct.

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  13. Transition metals usually from coloured complexes and d-d transitions ...

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  14. Transition metals usually from coloured complexes and d-d transitions ...

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  15. Pyrolusite ore on oxidation with KCIO(3)//KNO(3) in basic medium produ...

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  16. Pyrolusite ore on oxidation with KCIO(3)//KNO(3) in basic medium produ...

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  17. Pyrolusite ore on oxidation with KCIO(3)//KNO(3) in basic medium produ...

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  18. . Q. Which combination is correct:

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  19. . Q. Which combination is/are not correct

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  20. . Q. Which combination is correct for Ni.

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