(i) A powdered substance (A) on treatment with fusion mixture gives a green coloured compound (B). (ii) The solution of (B) in boiling water on acidification with dilute `H_(2)SO_(4)` gives a pink coloured compound `(C )`.
`(iii)` The aqueous solution of (A) on treatment with NaOH and `Br_(2)-` water gives a compound (D).
(iv) A solution of (D) in conc. `HNO_(3)` on treatment with lead peroxide at boiling temperature produced a compound (E) which was of the same coloure at that of (C).
(v) A solution of (A) on treatment with a solution of barium chloride gave a white precipitate of compound (F) Which was insoluble in conc. `HNO_(3)` and conc. HCl.
The oxidation state of central metal ions of (A), (B) and (C ) compounds are respectively `:`
(i) A powdered substance (A) on treatment with fusion mixture gives a green coloured compound (B). (ii) The solution of (B) in boiling water on acidification with dilute `H_(2)SO_(4)` gives a pink coloured compound `(C )`.
`(iii)` The aqueous solution of (A) on treatment with NaOH and `Br_(2)-` water gives a compound (D).
(iv) A solution of (D) in conc. `HNO_(3)` on treatment with lead peroxide at boiling temperature produced a compound (E) which was of the same coloure at that of (C).
(v) A solution of (A) on treatment with a solution of barium chloride gave a white precipitate of compound (F) Which was insoluble in conc. `HNO_(3)` and conc. HCl.
The oxidation state of central metal ions of (A), (B) and (C ) compounds are respectively `:`
`(iii)` The aqueous solution of (A) on treatment with NaOH and `Br_(2)-` water gives a compound (D).
(iv) A solution of (D) in conc. `HNO_(3)` on treatment with lead peroxide at boiling temperature produced a compound (E) which was of the same coloure at that of (C).
(v) A solution of (A) on treatment with a solution of barium chloride gave a white precipitate of compound (F) Which was insoluble in conc. `HNO_(3)` and conc. HCl.
The oxidation state of central metal ions of (A), (B) and (C ) compounds are respectively `:`
A
`+II,+VI and +VII`
B
`+II, +VI and +VI`
C
`+II,+VII and +VIII`
D
`+VI,+VII and +VII`
Text Solution
Verified by Experts
The correct Answer is:
A
(A) In `MnSO_(4),=+II,` (B) `MnO_(4)^(2-)=+VI,` (C) `MnO_(4)^(-)=+VII`
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(i) A powdered substance (A) on treatment with fusion mixture gives a green coloured compound (B). (ii) The solution of (B) in boiling water on acidification with dilute H_(2)SO_(4) gives a pink coloured compound (C ). (iii) The aqueous solution of (A) on treatment with NaOH and Br_(2)- water gives a compound (D). (iv) A solution of (D) in conc. HNO_(3) on treatment with lead peroxide at boiling temperature produced a compound (E) which was of the same colour at that of (C ) . (v) A solutionof ( A) on treatment with a solution of barium chloride gas a white precipitate of compound (F) which was insoluble in conc. HNO_(3) and conc. HCl. The oxidation state of central metal ions of (A) , (B) and (C) compounds are respectively.
(i) A powdered substance (A) on treatment with fusion mixture gives a green coloured compound (B). (ii) The solution of (B) in boiling water on acidification with dilute H_(2)SO_(4) gives a pink coloured compound (C ) . (iii) The aqueous solution of (A) on treatment with NaOH and Br_(2)- water gives a compound (D). (iv) A solution of (D) in conc. HNO_(3) on treatment with lead peroxide at boiling temperature produced a compound (E) which was of the same coloure at that of (C). (v) A solution of (A) on treatment with a solution of barium chloride gave a white precipitate of compound (F) Which was insoluble in conc. HNO_(3) and conc. HCl. Which of the following is true for compound (C ).
(i) A powdered substance (A) on treatment with fusion mixture gives a green coloured compound (B). (ii) The solution of (B) in boiling water on acidification with dilute H_(2)SO_(4) gives a pink coloured compound (C ). (iii) The aqueous solution of (A) on treatment with NaOH and Br_(2)- water gives a compound (D). (iv) A solution of (D) in conc. HNO_(3) on treatment with lead peroxide at boiling temperature produced a compound (E) which was of the same colour at that of (C ) . (v) A solutionof ( A) on treatment with a solution of barium chloride gas a white precipitate of compound (F) which was insoluble in conc. HNO_(3) and conc. HCl. Which of the following is true for compound (C ).
(i) A powdered substance (A) on treatment with fusion mixture gives a green coloured compound (B). (ii) The solution of (B) in boiling water on acidification with dilute H_(2)SO_(4) gives a pink coloured compound (C ) . (iii) The aqueous solution of (A) on treatment with NaOH and Br_(2)- water gives a compound (D). (iv) A solution of (D) in conc. HNO_(3) on treatment with lead peroxide at boiling temperature produced a compound (E) which was of the same coloure at that of (C). (v) A solution of (A) on treatment with a solution of barium chloride gave a white precipitate of compound (F) Which was insoluble in conc. HNO_(3) and conc. HCl. Consider the following statement : (I) Anions of both (B) and (C ) are diamagnetic and have tetradhedral geometray. (II) Anions of both (B) and ( C) are paramagnetic and have tetrahedral geometry. (III) Anions of (B) is paramagnetic and that of (C ) is diamagnetic but both have same tetrahedral geometry. (IV) Green coloured compound (B) in a neutral of acidic medium disproportionates to give (C ) and (D). Of these select the correct one from the code given :
(i) A powdered substance (A) on treatment with fusion mixture gives a green coloured compound (B). (ii) The solution of (B) in boiling water on acidification with dilute H_(2)SO_(4) gives a pink coloured compound (C ). (iii) The aqueous solution of (A) on treatment with NaOH and Br_(2)- water gives a compound (D). (iv) A solution of (D) in conc. HNO_(3) on treatment with lead peroxide at boiling temperature produced a compound (E) which was of the same colour at that of (C ) . (v) A solutionof ( A) on treatment with a solution of barium chloride gas a white precipitate of compound (F) which was insoluble in conc. HNO_(3) and conc. HCl. Consider the following statements : (I) An ions of both (B) and (C ) are diamagnetic and have tetradhedral geometry. (II) Anions of both (B) and (C ) are paramagnetic and have tetrahedral geometry. (C ) is diamagnetic but both have same tetrahedral geometry. (IV) Green coloured compound (B) in a neutral or acidic medium disproportionates to give (C ) and (D). Of these select the correct one from the codes given :
(a). A powdered substance (A) on treatment with fusion mixture gives a green coloured compound (B). (b). The solution of (B) The solution of (B) in boiling water on acidification with dilute H_2SO_4 gives a pink coloured compound (C).