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Which of the following is not acceptable...

Which of the following is not acceptable as resonating structure :

A

`overset(Theta)CH_(2)-overset(o+)underset(H)underset(|)N=O`

B

`CH_(2)=underset(H)underset(|)N=O`

C

`CH_(2)=overset(o+)underset(H)underset(|)N-O^(Theta)`

D

None of these

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AI Generated Solution

The correct Answer is:
To determine which of the given structures is not an acceptable resonating structure, we need to analyze the bonding and electron distribution in each option. Resonating structures must adhere to certain rules, including the following: 1. **All atoms must have a complete octet** (for second-period elements). 2. **The overall charge must remain the same** in all resonating structures. 3. **Bonds must not exceed the maximum valency** of the atoms involved. Now, let's analyze the options step-by-step: ### Step 1: Analyze Each Structure - **Option 1**: Check if all atoms have a complete octet and if the bonding is reasonable. - **Option 2**: Check for the nitrogen atom. If it has 5 bonds, this violates the octet rule, as nitrogen can only form a maximum of 4 bonds. - **Option 3**: Check if all atoms have a complete octet and if the bonding is reasonable. - **Option 4**: Check if all atoms have a complete octet and if the bonding is reasonable. ### Step 2: Identify the Incorrect Structure - Upon analyzing **Option 2**, we find that nitrogen has 5 bonds. This is not acceptable because nitrogen can only form a maximum of 4 bonds (due to its valency). Therefore, this structure is not a valid resonating structure. ### Conclusion The structure that is not acceptable as a resonating structure is **Option 2**. ---
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RESONANCE-GENERAL ORGANIC CHEMISTRY-I-EXERCISE-1 PART-II
  1. Which does not have conjugate system?

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  2. The compound which is not resonance stabilised

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  3. Which of the following is not acceptable as resonating structure :

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  4. Which of the following pair is not pair of resonating structures ?

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  5. Which of the following structures are resonance structures ?

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  6. Among the given sets, which represents the resonating structure?

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  7. In which of the following resonance is not possible ?

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  8. Which one of the following is least stable resonating structure ?

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  9. Which of the following resonating structure is the least contributing ...

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  10. HNCO (isocyanic acid) has following resonating structures : underset...

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  11. The correct stability order of the following resonanating structures i...

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  12. Which is the most stable resonating structure ?

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  13. Which of the following group show +Meffect ?

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  14. Which of the following group show -m effect?

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  15. Which of the following group show +M and -l effect?

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  16. Which of the following group shown +mgt - I effect?

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  17. Which of the following group show -m and -I effect?

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  18. +m and +I both effects are shown by:

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  19. The weakest +m group of the given species by:

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  20. Maximum extent of steric inhibition of resonance can be expected in

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