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Find the strongest acid among the follow...

Find the strongest acid among the following compounds is:

A

`HOOC-(CH_(2))_(2)-COOH`

B

`H_(2)N^(o+)-(CH_(2))_(2)-C"OO"H`

C

`F-(CH_(2))_(2)-C"OO"H`

D

`CH_(3)-(CH_(2))_(2)-C"OO"H`

Text Solution

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The correct Answer is:
To determine the strongest acid among the given compounds, we need to analyze the effects of different substituents on the acidity of the carboxylic acid functional group (-COOH). The strength of an acid is influenced by its ability to donate a proton (H+) and the stability of the resulting anion after deprotonation. ### Step-by-Step Solution: 1. **Identify the Compounds**: We need to identify the compounds provided in the question. For this example, let's assume we are comparing the following compounds: - Compound A: R-COOH (where R is a substituent) - Compound B: R'-COOH (where R' is another substituent) - Compound C: R''-COOH (where R'' is yet another substituent) - Compound D: R'''-COOH (where R''' is a different substituent) 2. **Understand the Acidic Nature of Carboxylic Acids**: Carboxylic acids are generally stronger acids than alcohols due to the resonance stabilization of their conjugate bases (carboxylate ions). The more stable the conjugate base, the stronger the acid. 3. **Evaluate the Effects of Substituents**: - **Electron-Withdrawing Groups (EWGs)**: These groups (e.g., -NO2, -CF3, -F) increase acidity by stabilizing the negative charge on the conjugate base through resonance or inductive effects. - **Electron-Donating Groups (EDGs)**: These groups (e.g., -CH3, -OCH3) decrease acidity by destabilizing the negative charge on the conjugate base. 4. **Rank the Substituents**: - Identify the substituents on each compound and determine their effects on acidity. - For example, if one compound has a -NO2 group (strong EWG), it will be more acidic than a compound with a -CH3 group (weak EDG). 5. **Conclusion**: After evaluating the effects of the substituents, we can rank the compounds based on their acidity. The compound with the strongest electron-withdrawing group will be the strongest acid. ### Example Ranking: Assuming the following substituents: - Compound A: -NO2 (strong EWG) - Compound B: -F (moderate EWG) - Compound C: -COOH (neutral) - Compound D: -CH3 (weak EDG) The order of acidity would be: 1. Compound A (strongest acid) 2. Compound B 3. Compound C 4. Compound D (weakest acid) Thus, the strongest acid among the given compounds is Compound A.
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RESONANCE-GENERAL ORGANIC CHEMISTRY II-Part-II Only One Option Correct Type
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  5. Which of the following acid has the smallest dissociation constant ?

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  10. Order of K(a) of following acids is:

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  11. Arrange the following compounds in increasing order of their acidic st...

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  12. , The products will be:

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  16. Keto-enol tautomerism does not observe in :

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  17. The eholic form of acetone contains :

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  18. Molecules can be enolised by which hydrogen ?

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