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2-Chlorobutane on treatment with alcohol...

2-Chlorobutane on treatment with alcoholic KOH/`Delta` gives major product :

A

2-Butene

B

1-Butene

C

2-Butanol

D

1-Butyne

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The correct Answer is:
To solve the problem of what major product is formed when 2-chlorobutane is treated with alcoholic KOH in the presence of heat, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactant is 2-chlorobutane, which has the following structure: ``` CH3-CH(Cl)-CH2-CH3 ``` - The reagent is alcoholic KOH, which is a strong base. 2. **Understand the Reaction Type**: - The reaction will proceed via an elimination mechanism, specifically the E2 mechanism. This mechanism involves the simultaneous removal of a hydrogen atom and a leaving group (in this case, Cl) to form a double bond. 3. **Determine the Beta Carbons**: - In the structure of 2-chlorobutane, the carbon atom bonded to the chlorine (the alpha carbon) is the second carbon. The beta carbons are the first and third carbons (C1 and C3). - The structure can be represented as: ``` C1: CH3 C2: CH(Cl) C3: CH2 C4: CH3 ``` 4. **Apply the Zaitsev's Rule**: - According to Zaitsev's rule, the more substituted alkene will be the major product. This means that the hydrogen will be removed from the beta carbon that has fewer hydrogen atoms. - Here, C1 (CH3) has 3 hydrogens, while C3 (CH2) has 2 hydrogens. Therefore, the hydrogen will be removed from C3. 5. **Elimination Process**: - When the hydrogen is removed from C3, the chlorine leaves, leading to the formation of a double bond between C2 and C3. - The resulting product will be: ``` CH3-CH=CH-CH3 ``` - This compound is 2-butene. 6. **Conclusion**: - The major product formed from the reaction of 2-chlorobutane with alcoholic KOH in the presence of heat is **2-butene**. ### Final Answer: The major product is **2-butene**. ---
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RESONANCE-ORGANIC REACTION MECHANISMS-IV-Exercise-1 Part-2
  1. Which of the following reaction is an example of elimination reaction ...

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  2. Correct statement for E1 Reaction is :

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  3. Intermediate formed during E1 reaction is -

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  4. CH3-undersetunderset(CH3)(|)CH-underset(Cl)underset(|)(CH)-CH3 overset...

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  5. CH3-undersetunderset(OH)(|)oversetoverset(CH3)(|)C-CH3 undersetDeltaov...

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  6. In the given reaction : overset(Conc. H2SO4)to [X] as major produ...

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  7. Identify the major formed in the following reaction

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  8. Which of the following does not represent the correct product?

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  9. Correct statement for E2 Reaction is :

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  10. Intermediate formed during E2 reaction is -

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  11. CH3-undersetunderset(H)(|)oversetoverset(CH3)(|)C-CH2Br underset(Delta...

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  12. Which of the following cannot undergo E2 reaction ? .

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  13. 2-Chlorobutane on treatment with alcoholic KOH/Delta gives major produ...

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  14. CH3-undersetunderset(CH3)(|)CH-oversetoverset(Cl)(|)CH-CH3 underset(De...

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  15. X and Y are respectively :

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  16. Identify the major products in the following reactions ? CH3-CH2-und...

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  17. Reaction intermediate of E1cB reaction is :

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  18. D-exchange is observed in :

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  19. Major Product is :

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  20. Major product of given reaction is - O2N-CH2-undersetunderset(Cl)(|)...

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