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If K(p) for a reaction is 0.1 at 27^(@)C...

If `K_(p)` for a reaction is 0.1 at `27^(@)C` the `K_(c )` of the reaction will be

A

can not be calculate as `Delta n_(g) ` is not given

B

`(K_(p))/( RT)`

C

`K_(p) RT`

D

`(K_(p))/( ( RT)^(2))`

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The correct Answer is:
To find the value of \( K_c \) from the given \( K_p \) for a reaction, we can use the following relationship: \[ K_p = K_c (RT)^{\Delta n} \] Where: - \( K_p \) is the equilibrium constant in terms of partial pressures. - \( K_c \) is the equilibrium constant in terms of concentrations. - \( R \) is the universal gas constant (0.0821 L·atm/(K·mol)). - \( T \) is the temperature in Kelvin. - \( \Delta n \) is the change in the number of moles of gas (moles of gaseous products - moles of gaseous reactants). ### Step-by-Step Solution: 1. **Convert Temperature to Kelvin**: \[ T = 27^\circ C + 273.15 = 300.15 \, K \] 2. **Identify Given Values**: \[ K_p = 0.1 \] \[ R = 0.0821 \, L·atm/(K·mol) \] 3. **Determine \(\Delta n\)**: For this step, we need to know the balanced chemical equation to find \(\Delta n\). Assuming a general reaction: \[ aA(g) + bB(g) \rightleftharpoons cC(g) + dD(g) \] Then, \[ \Delta n = (c + d) - (a + b) \] For simplicity, let's assume \(\Delta n = 1\) (you can adjust based on the actual reaction). 4. **Use the Relationship**: Substitute the known values into the equation: \[ K_p = K_c (RT)^{\Delta n} \] Rearranging gives: \[ K_c = \frac{K_p}{(RT)^{\Delta n}} \] 5. **Calculate \(K_c\)**: \[ K_c = \frac{0.1}{(0.0821 \times 300.15)^1} \] \[ K_c = \frac{0.1}{24.726} \] \[ K_c \approx 0.00404 \] ### Final Answer: \[ K_c \approx 0.00404 \]
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