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The average velocity of CO(2) at T K is ...

The average velocity of `CO_(2)` at T K is `9 xx 10^(4) cm s^(-1)`. The value of T is

A

1682.5K

B

2143.37

C

373.20K

D

1240 K

Text Solution

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The correct Answer is:
To find the value of T (temperature in Kelvin) given the average velocity of CO₂, we can use the formula for average molecular speed: \[ v = \sqrt{\frac{8RT}{\pi m}} \] Where: - \( v \) = average velocity (in m/s) - \( R \) = universal gas constant (8.314 J/(mol·K)) - \( T \) = temperature in Kelvin - \( m \) = molecular mass (in kg) ### Step 1: Convert the given average velocity from cm/s to m/s The average velocity of CO₂ is given as \( 9 \times 10^4 \) cm/s. To convert this to m/s, we divide by 100: \[ v = \frac{9 \times 10^4 \text{ cm/s}}{100} = 9 \times 10^2 \text{ m/s} \] ### Step 2: Determine the molecular mass of CO₂ The molecular mass of CO₂ can be calculated as follows: - Carbon (C) = 12 g/mol - Oxygen (O) = 16 g/mol (and there are two oxygen atoms in CO₂) Thus, the molecular mass of CO₂ is: \[ m = 12 + 2 \times 16 = 12 + 32 = 44 \text{ g/mol} \] To convert this to kg, we divide by 1000: \[ m = \frac{44 \text{ g/mol}}{1000} = 0.044 \text{ kg/mol} \] ### Step 3: Substitute known values into the average velocity formula Now we can substitute the values into the formula: \[ 9 \times 10^2 = \sqrt{\frac{8 \times 8.314 \times T}{\pi \times 0.044}} \] ### Step 4: Square both sides to eliminate the square root Squaring both sides gives: \[ (9 \times 10^2)^2 = \frac{8 \times 8.314 \times T}{\pi \times 0.044} \] Calculating the left side: \[ (9 \times 10^2)^2 = 81 \times 10^4 = 8100000 \] ### Step 5: Rearrange the equation to solve for T Rearranging the equation gives: \[ T = \frac{8100000 \times \pi \times 0.044}{8 \times 8.314} \] ### Step 6: Calculate the value of T Using \( \pi \approx 3.14 \): \[ T = \frac{8100000 \times 3.14 \times 0.044}{8 \times 8.314} \] Calculating the numerator: \[ 8100000 \times 3.14 \times 0.044 \approx 1.116 \times 10^6 \] Calculating the denominator: \[ 8 \times 8.314 \approx 66.512 \] Now, dividing: \[ T \approx \frac{1.116 \times 10^6}{66.512} \approx 16825.4 \text{ K} \] ### Final Answer Thus, the value of T is approximately: \[ T \approx 168.25 \text{ K} \]
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