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Which of the following curves obtained a...

Which of the following curves obtained at constant temperature and for a given mass of a gas is not a straight line ?

A

P vs V

B

P vs `( 1//V )`

C

V vs ( `1//P ` )

D

(PV ) vs P

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question of which curve obtained at constant temperature and for a given mass of a gas is not a straight line, we will analyze the relationships between pressure (P), volume (V), and the ideal gas law. ### Step-by-Step Solution: 1. **Understand the Ideal Gas Law**: The ideal gas equation is given by: \[ PV = nRT \] where \( P \) is the pressure, \( V \) is the volume, \( n \) is the number of moles of gas, \( R \) is the universal gas constant, and \( T \) is the temperature. 2. **Given Conditions**: We are told that the temperature is constant and we have a given mass of gas. This means that the number of moles \( n \) is constant, as it is determined by the mass of the gas divided by its molar mass. 3. **Rearranging the Equation**: For a constant mass of gas at constant temperature, we can express the ideal gas law as: \[ PV = K \] where \( K = nRT \) is a constant. 4. **Analyzing the Relationship**: Rearranging gives: \[ P = \frac{K}{V} \] This indicates that pressure and volume are inversely related. 5. **Graph of P vs V**: When plotting \( P \) against \( V \), we get a hyperbolic curve, which is not a straight line. This is because as volume increases, pressure decreases, and vice versa. 6. **Other Relationships**: - If we plot \( P \) against \( \frac{1}{V} \): \[ P = K \cdot \frac{1}{V} \] This relationship is linear, and the graph will be a straight line passing through the origin. - If we plot \( V \) against \( \frac{1}{P} \): \[ V = K \cdot \frac{1}{P} \] This is also a linear relationship, resulting in a straight line through the origin. - If we plot \( PV \) against \( P \): Since \( PV = K \), this will also yield a straight line, but it will not pass through the origin (as \( K \) is a constant greater than zero). 7. **Conclusion**: The only relationship that does not yield a straight line is the graph of \( P \) versus \( V \), which is a hyperbola. Therefore, the curve that is not a straight line is the one representing the relationship between pressure and volume at constant temperature and a given mass of gas. ### Final Answer: The curve obtained at constant temperature and for a given mass of gas that is not a straight line is the graph of \( P \) versus \( V \).
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