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X hArr nY, X decomposes to give Y ( in o...

`X hArr nY, X` decomposes to give Y ( in one lietre vessel ) if degree of dissociation is `alpha` then `K_( C )` `:`

A

`( (n alpha))/( ( 1+alpha))`

B

`( (n alpha))/( ( 1- alpha)) `

C

`(n alpha)/((1- alpha)) `

D

`((n alpha)^(n))/((1- alpha))`

Text Solution

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The correct Answer is:
To solve the problem, we need to determine the equilibrium constant \( K_c \) for the reaction \( X \rightleftharpoons nY \) given the degree of dissociation \( \alpha \). ### Step-by-Step Solution: 1. **Write the Reaction**: The reaction is given as: \[ X \rightleftharpoons nY \] 2. **Define Initial Concentrations**: Let's assume we start with 1 mole of \( X \) in a 1-liter vessel. Therefore, the initial concentration of \( X \) is: \[ [X]_0 = 1 \, \text{mol/L} \] The initial concentration of \( Y \) is: \[ [Y]_0 = 0 \, \text{mol/L} \] 3. **Degree of Dissociation**: The degree of dissociation \( \alpha \) represents the fraction of \( X \) that has dissociated. Thus, at equilibrium: - The amount of \( X \) that dissociates is \( \alpha \) moles. - The amount of \( Y \) produced is \( n\alpha \) moles. 4. **Calculate Equilibrium Concentrations**: At equilibrium, the concentrations will be: \[ [X] = 1 - \alpha \, \text{mol/L} \] \[ [Y] = n\alpha \, \text{mol/L} \] 5. **Write the Expression for \( K_c \)**: The equilibrium constant \( K_c \) for the reaction is given by: \[ K_c = \frac{[Y]^n}{[X]} \] 6. **Substitute the Equilibrium Concentrations into the \( K_c \) Expression**: Substituting the equilibrium concentrations into the expression for \( K_c \): \[ K_c = \frac{(n\alpha)^n}{(1 - \alpha)} \] 7. **Final Expression for \( K_c \)**: Thus, the final expression for the equilibrium constant \( K_c \) is: \[ K_c = \frac{(n\alpha)^n}{(1 - \alpha)} \] ### Summary: The value of \( K_c \) for the reaction \( X \rightleftharpoons nY \) when the degree of dissociation is \( \alpha \) is: \[ K_c = \frac{(n\alpha)^n}{(1 - \alpha)} \]
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