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In the reaction Me(3)N overset(BrCN)to...

In the reaction
`Me_(3)N overset(BrCN)toA underset((ii)Delta)overset((i)H_(2)O)toB`
B is

A

`MeNH_(2)`

B

`Me_(3)NO`

C

`Me_(2)NH`

D

`Me_(2)NCOOH`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the given reaction step by step. ### Step 1: Identify the starting compound The starting compound is trimethylamine, represented as \( \text{Me}_3\text{N} \). It has three methyl groups attached to a nitrogen atom. ### Step 2: Understand the reaction with BrCN In the first part of the reaction, \( \text{Me}_3\text{N} \) reacts with \( \text{BrCN} \). The bromine (Br) atom is a good leaving group, and the cyanide group (CN) can act as a nucleophile. The nitrogen atom in trimethylamine has a lone pair of electrons and can attack the carbon of the cyanide group. ### Step 3: Formation of compound A When \( \text{Me}_3\text{N} \) reacts with \( \text{BrCN} \), the bromine atom leaves, and the nitrogen forms a bond with the carbon of the cyanide group. This results in the formation of a new compound, which can be represented as \( \text{Me}_3\text{N}^+\text{C} \equiv \text{N} \) (a quaternary ammonium salt with a cyanide group). This compound is denoted as \( A \). ### Step 4: Heating the compound A The next step involves heating compound \( A \) under conditions denoted by \( (ii) \Delta \). Heating can lead to the hydrolysis of the cyanide group. The cyanide group can be converted into a carboxylic acid through hydrolysis. ### Step 5: Formation of compound B When compound \( A \) is hydrolyzed, the cyanide group (\( -C \equiv N \)) will be converted into a carboxylic acid group (\( -COOH \)). Thus, the final product \( B \) will be trimethylamine with a carboxylic acid group attached, which is trimethylammonium carboxylate. ### Conclusion The final product \( B \) is trimethylammonium carboxylate. ### Summary of the Steps: 1. Identify the starting compound as trimethylamine (\( \text{Me}_3\text{N} \)). 2. Recognize the reaction with \( \text{BrCN} \) leading to the formation of compound \( A \). 3. Understand that heating compound \( A \) leads to hydrolysis. 4. Conclude that the final product \( B \) is trimethylammonium carboxylate.
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