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Which of the following statements regard...

Which of the following statements regarding the molecule `CH_(2)=C=CH_(2)` is NOT correct?

A

Both the `pi` bonds are present in the same plane

B

The central carbon atom is sp hybridized while the terminal atoms are `sp^(2)` hybridized

C

the molecular is linear

D

the molecule contains six `sigma` bonds and two `pi` bonds.

Text Solution

AI Generated Solution

The correct Answer is:
To determine which statement regarding the molecule `CH₂=C=CH₂` (allene) is NOT correct, we will analyze the properties and characteristics of the molecule step by step. ### Step 1: Identify the Structure of Allene The molecule `CH₂=C=CH₂` is known as allene. It consists of three carbon atoms and is characterized by having two double bonds between the central carbon and the two terminal carbons. **Hint:** Remember that allene has a unique structure due to the arrangement of its double bonds. ### Step 2: Count Sigma and Pi Bonds In allene: - Each carbon atom forms sigma (σ) bonds with hydrogen and other carbon atoms. - The double bonds consist of one sigma bond and one pi (π) bond each. For `CH₂=C=CH₂`: - The central carbon (C) is bonded to two terminal carbons (C) and has two pi bonds. - Total sigma bonds = 6 (2 from each C-H bond and 1 from each C-C bond). - Total pi bonds = 2 (one from each double bond). **Hint:** Count the bonds carefully; remember that each double bond consists of one sigma and one pi bond. ### Step 3: Determine Hybridization - The terminal carbon atoms (C) are involved in three sigma bonds (two with hydrogen and one with the central carbon), indicating they are sp² hybridized. - The central carbon atom is involved in two sigma bonds and two pi bonds, indicating it is sp hybridized. **Hint:** Recall that sp hybridization occurs when there are two sigma bonds and sp² hybridization occurs when there are three sigma bonds. ### Step 4: Analyze Molecular Geometry - The geometry of the allene molecule is linear due to the arrangement of the double bonds. The two pi bonds are perpendicular to each other, which is a unique feature of allenes. **Hint:** Consider how the geometry affects the molecular shape and bond angles. ### Step 5: Evaluate the Given Statements Now, let's evaluate the statements regarding the molecule: 1. Both pi bonds are in the same plane. (This is NOT correct; they are perpendicular to each other.) 2. The central atom is sp hybridized, and the terminal atoms are sp² hybridized. (This is correct.) 3. The molecule is linear. (This is correct.) 4. The molecule contains 6 sigma bonds and 2 pi bonds. (This is correct.) ### Conclusion The statement that is NOT correct is: **"Both pi bonds are in the same plane."** ### Final Answer The answer to the question is that the statement "Both pi bonds are in the same plane" is NOT correct regarding the molecule `CH₂=C=CH₂`.
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