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H(3)C-CH(2)-underset(Br)underset(|)(C)H-...

`H_(3)C-CH_(2)-underset(Br)underset(|)(C)H-CH_(3) overset(NaNH_(2))to`
Which are correct statement?

A

1-butene is Hofman product

B

2-butene is saytzeff product

C

both are correct

D

none is correct

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem regarding the reaction of 2-bromobutane with sodium amide (NaNH2), we will analyze the reaction step by step. ### Step-by-Step Solution: 1. **Identify the Reactant**: The given compound is 2-bromobutane, which can be represented as: \[ \text{CH}_3-\text{CH}_2-\text{C}(\text{Br})-\text{CH}_3 \] 2. **Understand the Reagent**: Sodium amide (NaNH2) is a strong base. It can deprotonate hydrogen atoms from the adjacent carbon atoms (alpha hydrogens) to the carbon bearing the bromine atom. 3. **Possible Deprotonation**: The base (NaNH2) can abstract a proton from either of the two adjacent carbon atoms (the one on the left or the one on the right of the carbon attached to Br): - If it abstracts a proton from the left carbon (CH2), the double bond will form between the left carbon and the carbon with Br, leading to the formation of 1-butene. - If it abstracts a proton from the right carbon (CH3), the double bond will form between the carbon with Br and the right carbon, leading to the formation of 2-butene. 4. **Determine the Products**: - **Hofmann Product**: This is the less substituted alkene, which in this case is 1-butene (formed by deprotonating the left carbon). - **Saytzeff Product (Zaitsev's Rule)**: This is the more substituted alkene, which is 2-butene (formed by deprotonating the right carbon). 5. **Conclusion**: - The reaction produces both 1-butene (Hofmann product) and 2-butene (Saytzeff product). - Therefore, the correct statements regarding the products of the reaction are: - 1-butene is a Hofmann product. - 2-butene is a Saytzeff product. - Both statements are correct. ### Final Answer: - The correct options are: 1. 1-butene is a Hofmann product. 2. 2-butene is a Saytzeff product. 3. Both are correct.
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