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Greatest amount of hydration is in...

Greatest amount of hydration is in

A

B

C

D

all are equal

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The correct Answer is:
To determine where the greatest amount of hydration occurs, we need to analyze the options provided and understand the concept of hydration in organic chemistry. ### Step-by-Step Solution: 1. **Understanding Hydration**: - Hydration refers to the addition of water (H₂O) to a compound. In organic chemistry, this often involves the nucleophilic attack of the hydroxide ion (OH⁻) on an electrophilic center, typically a carbon atom that is electron-deficient. 2. **Identifying Electrophilic Centers**: - The carbonyl carbon (C=O) in aldehydes and ketones is a common site for nucleophilic attack due to its electron deficiency. We need to identify which compound has the most electrophilic carbonyl carbon. 3. **Analyzing the Options**: - Let's consider the options provided: - **Option 1**: A compound with a ring structure. - **Option 2**: A compound with a bromine substituent (Br) that exerts a -I (inductive) effect, decreasing electron density. - **Option 3**: A compound with a bromine substituent and a carbonyl group, likely an aldehyde. 4. **Evaluating the Effects of Substituents**: - The -I effect of bromine pulls electron density away from the carbonyl carbon, making it more electrophilic. - In the case of aldehydes (like in Option 3), the carbonyl carbon is more electrophilic than in ketones due to the presence of hydrogen atoms, which do not exert a strong electron-withdrawing effect compared to alkyl groups. 5. **Comparing Electrophilicity**: - Between the options, the compound in Option 3, which is an aldehyde, will have a more pronounced electrophilic character due to the influence of the bromine atom and the nature of the aldehyde functional group. 6. **Conclusion**: - The greatest amount of hydration will occur in the compound represented by **Option 3**, as it has the most favorable conditions for nucleophilic attack by the hydroxide ion. ### Final Answer: The greatest amount of hydration is in **Option 3**. ---
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