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The amine A (C(4)H(11)N) reacts with ben...

The amine A `(C_(4)H_(11)N)` reacts with benzene sulphonyl chloride gives a product which is insoluble in aqueous NaOH then the number of alkyl group directly attached to nitrogen atom will be.

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To solve the problem, we need to analyze the given information about the amine A (C₄H₁₁N) and its reaction with benzene sulphonyl chloride. We will determine the number of alkyl groups directly attached to the nitrogen atom. ### Step-by-Step Solution: 1. **Identify the Structure of Amine A:** The molecular formula of amine A is C₄H₁₁N. We need to determine the possible structures for this amine. The presence of nitrogen suggests that it can be a primary, secondary, or tertiary amine. 2. **Calculate the Degree of Unsaturation:** The degree of unsaturation can be calculated using the formula: \[ \text{Degree of Unsaturation} = \frac{(C + N - H + 1)}{2} \] Here, C = 4, H = 11, and N = 1. \[ \text{Degree of Unsaturation} = \frac{(4 + 1 - 11 + 1)}{2} = \frac{-5}{2} = 0 \] A degree of unsaturation of 0 indicates that there are no rings or double bonds in the structure. 3. **Determine the Type of Amine:** Since the degree of unsaturation is 0, amine A must be a saturated compound. Given that it reacts with benzene sulphonyl chloride and forms a product that is insoluble in aqueous NaOH, we can deduce that amine A is likely a **secondary amine**. This is because primary amines typically form soluble sulphonamides in NaOH. 4. **Analyze the Reaction with Benzene Sulphonyl Chloride:** The reaction of amines with benzene sulphonyl chloride results in the formation of sulphonamides. For a secondary amine (R₂NH), the reaction can be represented as: \[ R_2NH + ArSO_2Cl \rightarrow R_2N-SO_2Ar + HCl \] The product formed from a secondary amine will have two alkyl groups (R) attached to the nitrogen atom. 5. **Conclusion:** Since we have established that amine A is a secondary amine, the number of alkyl groups directly attached to the nitrogen atom is **2**. ### Final Answer: The number of alkyl groups directly attached to the nitrogen atom in amine A is **2**.
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