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Which metal bicarbonates does not exist ...

Which metal bicarbonates does not exist in solid state?
(i)`LiHCO_(3)` (ii)`Ca(HCO_(3))_(2)` (iii)`Zn(HCO_(3))_(2)` (iv)`CaS_(2)O_(3)`

Text Solution

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The correct Answer is:
A
Only bicarbonate salt of alkali metals are found in solid state.
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Alkali metals readily react with oxyacids forming corresponding salts like M_(2)CO_(3),MHCO_(3),MNO_(3),M_(2)SO_(4) etc. with evolution of hydrogen. The also dissolve in liquid NH_(3) but without the evolution of hydrogen. The colour of its dilute solution is blue but when it is heated and concentrated then is colour becomes bronze. Which metal bicarbonate does not exist in solid state? {:(,(P),LiHCO_(3)," ",(Q),Ca(HCO_(3))_(2)),(,(R),Zn(HCO_(3))_(2)," ",(S),NaHCO_(3)),(,(T),AgHCO_(3)," ",,):}

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How many of the following bicarbonates are solid in nature? LiHCO_(3),NaHCO_(3),KHCO_(3),RbHCO_(3),CaHCO_(3),CsHCO_(3), Be(HCO_(3))_(2), Mg(HCO_(3))_(2),Ca(HCO_(3))_(2)Sr(HCO_(3))_(2),Ba(HCO_(3))_(2)