NO+NO(2) overset(-11^(@)C) to N(2)O(3)...

`NO+NO_(2) overset(-11^(@)C) to N_(2)O_(3)`

For disproportionation reaction.

For comproportionation reaction.

For either intermolecular redox reaction or displacement reaction

For either thermal combination redox reaction or thermal decomposition redox reaction.

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Consider a system containing NO_(2) and SO_(2) in which NO_(2) is consumed in the following two parallel reactions. 2NO_(2) overset(K_(1)) to N_(2)O_(4), NO_(2) + SO_(2) overset(K_(2)) to NO + SO_(3) The rate of disappearance of NO_(2) will be equal to

NH_(4)NO_(3) overset(Delta) to N_(2)O+H_(2)O

N_(2)O_(3) overset(R.T.) to NO+NO_(2)

Pb(NO_(3))_(2) overset(Delta)to PbO+NO_(2)+O_(2)

The rate law for the decompoistion of gaseous N_(2)O_(5) , N_(2)O_(5)(g) rarr 2NO_(2)(g) + (1)/(2)O_(2)(g) is observed to be: r = (-d[N_(2)O_(5)])/(dt) = k[N_(2)O_(5)] A reaction machanism which has been suggested to be conisstent with this rate law is N_(2)O_(5)(g) overset(k_(eq))hArr NO_(2)(g)+NO_(3)(g) ("fast equilibrium") NO_(2) (g) + NO_(3)(g) overset(k_(1))rarr NO_(2)(g) + NO(g) + O_(2)(g) (slow) NO(g) + NO_(3)(g) overset(k_(2))rarr 2NO_(2)(g) (fast)

The reaction f NO_(2)(g) and O_(3)(g) is first-order in NO_(2) and O_(3)(g) 2NO_(2)(g) +O_(3)(g) rarr N_(2)O_(5)(g) + O_(2)(g) The reaction can take place by mechansim: (P) NO_(2)+O_(3) overset("slow") rarr NO_(3)+O_(2) NO_(3)+NO_(2) overset("fast")rarr N_(2)O_(5) (Q) O_(3)underset(k_(b)) overset(k_(a) "fast")hArr O_(2)+[O] NO_(2) +O overset("slow")rarr NO_(3) NO_(3) +NO_(2) overset("fast")rarr N_(2)O_(5) Select the correct mechanism.

In the following reaction: 2NO(g)+O_(2)(g) overset(k')rarr2NO_(2)(g) What is the predicted rate law, if the mechanism is NO+O_(2)(g) overset(k_(eq))hArr NO_(3) ("fast") (fast) NO_(3) + NO overset(k_(1))rarr NO_(2) + NO_(2) (slow)

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NO+NO(2) overset(-11^(@)C) to N(2)O(3)
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