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Two flasks A and B of equal volume conta...

Two flasks A and B of equal volume containing equal masses of `H_2 and CH_4` gases are at 100 K and 200 K temperature, respectively. Which of the following is true about the total KE (kinetic energy) ?

A

Total KE of `H_2` is four times that of `CH_4`

B

Total KE of `CH_4` is four times that of `H_2`

C

Total KE of `H_2` is two times that of `CH_4`

D

Total KE of `CH_4` is two times that of `H_2`

Text Solution

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The correct Answer is:
To solve the problem regarding the total kinetic energy (KE) of the gases in flasks A and B, we will follow these steps: ### Step 1: Identify the given data - Flask A contains Hydrogen gas (H₂) at a temperature of 100 K. - Flask B contains Methane gas (CH₄) at a temperature of 200 K. - Both flasks have equal volumes and contain equal masses of gases. ### Step 2: Calculate the number of moles of each gas - The molar mass of H₂ = 2 g/mol. - The molar mass of CH₄ = 16 g/mol. - Let the mass of each gas in the flasks be 'm'. Using the formula for moles: \[ n = \frac{m}{M} \] - Moles of H₂, \( n_{H2} = \frac{m}{2} \) - Moles of CH₄, \( n_{CH4} = \frac{m}{16} \) ### Step 3: Write the formula for total kinetic energy The total kinetic energy (KE) of an ideal gas can be expressed as: \[ KE = \frac{3}{2} nRT \] Where: - \( n \) = number of moles - \( R \) = universal gas constant - \( T \) = temperature in Kelvin ### Step 4: Calculate the total kinetic energy for each gas - For H₂ at 100 K: \[ KE_{H2} = \frac{3}{2} \left(\frac{m}{2}\right) R (100) \] - For CH₄ at 200 K: \[ KE_{CH4} = \frac{3}{2} \left(\frac{m}{16}\right) R (200) \] ### Step 5: Simplify the expressions for kinetic energy - For H₂: \[ KE_{H2} = \frac{3mR}{4} \times 100 = \frac{300mR}{4} = 75mR \] - For CH₄: \[ KE_{CH4} = \frac{3mR}{32} \times 200 = \frac{600mR}{32} = \frac{75mR}{4} \] ### Step 6: Compare the total kinetic energies Now, we can compare the two kinetic energies: - \( KE_{H2} = 75mR \) - \( KE_{CH4} = \frac{75mR}{4} \) ### Step 7: Determine the relationship From the calculations: \[ KE_{H2} = 4 \times KE_{CH4} \] This means the total kinetic energy of H₂ is four times that of CH₄. ### Conclusion The total kinetic energy of the Hydrogen gas (H₂) is greater than that of Methane gas (CH₄) by a factor of 4. ---
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