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If 100 mL of 1 N H(2)SO(4) is mixed with...

If 100 mL of `1 N H_(2)SO_(4)` is mixed with 100 mL of 1 M NaOH solution. The resulting solution will be

A

Highly acidic

B

Neutral

C

Highly basic

D

Slightly acidic

Text Solution

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The correct Answer is:
To solve the problem of mixing 100 mL of 1 N H₂SO₄ with 100 mL of 1 M NaOH, we will follow these steps: ### Step 1: Determine the moles of H₂SO₄ 1. **Calculate the normality and convert it to molarity**: - Given: Normality (N) of H₂SO₄ = 1 N - H₂SO₄ can donate 2 protons (H⁺), so its n-factor = 2. - Molarity (M) = Normality (N) / n-factor = 1 N / 2 = 0.5 M. 2. **Calculate the volume in liters**: - Volume of H₂SO₄ = 100 mL = 100 / 1000 = 0.1 L. 3. **Calculate moles of H₂SO₄**: - Moles of H₂SO₄ = Molarity × Volume = 0.5 M × 0.1 L = 0.05 moles. ### Step 2: Determine the moles of NaOH 1. **Given**: Molarity (M) of NaOH = 1 M. 2. **Calculate the volume in liters**: - Volume of NaOH = 100 mL = 100 / 1000 = 0.1 L. 3. **Calculate moles of NaOH**: - Moles of NaOH = Molarity × Volume = 1 M × 0.1 L = 0.1 moles. ### Step 3: Write the balanced chemical equation - The reaction between H₂SO₄ and NaOH is: \[ H₂SO₄ + 2 NaOH \rightarrow Na₂SO₄ + 2 H₂O \] - From the equation, 1 mole of H₂SO₄ reacts with 2 moles of NaOH. ### Step 4: Determine the limiting reactant 1. **Calculate the required moles of NaOH for the available moles of H₂SO₄**: - For 0.05 moles of H₂SO₄, the required moles of NaOH = 0.05 moles H₂SO₄ × 2 = 0.1 moles NaOH. 2. **Compare with available moles of NaOH**: - Available moles of NaOH = 0.1 moles. - Since both the required and available moles of NaOH are equal, both reactants are completely consumed. ### Step 5: Determine the nature of the resulting solution - Since both the acid (H₂SO₄) and the base (NaOH) are completely neutralized, the resulting solution will be neutral. - The pH of a neutral solution is 7. ### Conclusion The resulting solution after mixing 100 mL of 1 N H₂SO₄ with 100 mL of 1 M NaOH is **neutral**. ---
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