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A: In the reaction, 2NaOH+H(2)SO(4) to...

A: In the reaction,
`2NaOH+H_(2)SO_(4) to Na_(2)SO_(4) + 2H_(2)O`
equivalents of NaOH, `Na_(2)SO_(4)` and `H_(2)SO_(4)` are equal.
R: `"Number of equivalents" = "number of moles" xx "n-factor"`.

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion

C

If Assertion is true statement but Reason is false

D

If both Assertion and Reason are false statements

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given problem, we need to analyze the assertion and reason statements regarding the reaction between sodium hydroxide (NaOH) and sulfuric acid (H₂SO₄). ### Step-by-Step Solution: 1. **Identify the Reaction**: The reaction given is: \[ 2 \text{NaOH} + \text{H}_2\text{SO}_4 \rightarrow \text{Na}_2\text{SO}_4 + 2 \text{H}_2\text{O} \] 2. **Understanding the Assertion**: The assertion states that the equivalents of NaOH, Na₂SO₄, and H₂SO₄ are equal. To verify this, we need to calculate the number of equivalents for each substance involved in the reaction. 3. **Calculate the n-factor**: - **For NaOH**: - NaOH dissociates to give one hydroxide ion (OH⁻) per molecule. - Therefore, the n-factor of NaOH is 1. - **For H₂SO₄**: - H₂SO₄ dissociates to give two H⁺ ions per molecule. - Therefore, the n-factor of H₂SO₄ is 2. - **For Na₂SO₄**: - Na₂SO₄ does not provide any H⁺ or OH⁻ ions in this context, so its n-factor is 0 for this reaction. 4. **Calculate the Number of Equivalents**: Using the formula: \[ \text{Number of equivalents} = \text{Number of moles} \times \text{n-factor} \] - Let’s assume we have 1 mole of H₂SO₄, which means we have 2 moles of NaOH reacting with it. - For 2 moles of NaOH: \[ \text{Equivalents of NaOH} = 2 \, \text{moles} \times 1 = 2 \, \text{equivalents} \] - For 1 mole of H₂SO₄: \[ \text{Equivalents of H₂SO₄} = 1 \, \text{mole} \times 2 = 2 \, \text{equivalents} \] - For Na₂SO₄, since it does not contribute to the reaction in terms of H⁺ or OH⁻, we consider its equivalents as 0 in this context. 5. **Conclusion**: Since the equivalents of NaOH and H₂SO₄ are equal (2 equivalents each), the assertion is true. The reason provided is also true as it correctly states how to calculate the number of equivalents. ### Final Answer: Both the assertion and reason are true, and the reason is the correct explanation of the assertion. Therefore, the correct answer is option 1.
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