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A: 50 ml, decinormal HCl when mixed with...

A: 50 ml, decinormal HCl when mixed with 50 ml, decinormal `H_(2) SO_(4)`, then normality of `H^(+)` ion in resultant solution is 0.1 N.
R: Here, `MV = M_(1)V_(1) - M_(2)V_(2)`

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion

C

If Assertion is true statement but Reason is false

D

If both Assertion and Reason are false statements

Text Solution

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The correct Answer is:
To solve the problem, we need to determine the normality of the \( H^+ \) ions in the resultant solution when 50 mL of decinormal \( HCl \) is mixed with 50 mL of decinormal \( H_2SO_4 \). ### Step-by-Step Solution: 1. **Understand the Normality of the Solutions**: - Decinormal \( HCl \) means it has a normality of \( 0.1 \, N \) (1 decinormal = \( \frac{1}{10} \, N \)). - Decinormal \( H_2SO_4 \) also has a normality of \( 0.1 \, N \). 2. **Calculate the Number of Equivalents**: - For \( HCl \): \[ \text{Normality} (N_1) = 0.1 \, N, \quad \text{Volume} (V_1) = 50 \, mL = 0.050 \, L \] \[ \text{Equivalents of } HCl = N_1 \times V_1 = 0.1 \times 0.050 = 0.005 \, \text{equivalents} \] - For \( H_2SO_4 \): \[ \text{Normality} (N_2) = 0.1 \, N, \quad \text{Volume} (V_2) = 50 \, mL = 0.050 \, L \] Since \( H_2SO_4 \) can donate 2 \( H^+ \) ions, the number of equivalents will be: \[ \text{Equivalents of } H_2SO_4 = N_2 \times V_2 \times 2 = 0.1 \times 0.050 \times 2 = 0.01 \, \text{equivalents} \] 3. **Total Equivalents of \( H^+ \) Ions**: - Total equivalents of \( H^+ \) ions from both acids: \[ \text{Total } H^+ = 0.005 + 0.01 = 0.015 \, \text{equivalents} \] 4. **Calculate the Total Volume of the Solution**: - The total volume after mixing: \[ V_{total} = V_1 + V_2 = 50 \, mL + 50 \, mL = 100 \, mL = 0.1 \, L \] 5. **Determine the Normality of \( H^+ \) Ions in the Resultant Solution**: - Normality (\( N \)) of \( H^+ \) ions: \[ N = \frac{\text{Total equivalents}}{\text{Total volume in L}} = \frac{0.015}{0.1} = 0.15 \, N \] 6. **Final Result**: - The normality of \( H^+ \) ions in the resultant solution is \( 0.15 \, N \).
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