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A : The radius of second orbit of h...

A : The radius of second orbit of ` he^(+)` is equal to that of first orbit of hydrogen
R : The radius of an orbit in hydrogen like species is directly proportional to n and inversely proportional to Z .

A

IF both assertion & reason are true and the reason is the correct explanation of the assertion then mark

B

IF both assertion & reason are true but the reason is not the correct explanation of the assertion , then mark

C

IF assertion is true statement but reason is false , then mark

D

If both assertion and reason are false statements then mark

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given question, we need to analyze both the assertion (A) and the reason (R) provided. ### Step 1: Understand the Assertion The assertion states that the radius of the second orbit of \( \text{He}^+ \) is equal to the radius of the first orbit of hydrogen. ### Step 2: Use the Bohr Model Formula According to the Bohr model, the radius of the nth orbit for a hydrogen-like atom is given by the formula: \[ R_n = \frac{0.53 \, n^2}{Z} \, \text{Å} \] where: - \( R_n \) is the radius of the nth orbit, - \( n \) is the principal quantum number (1 for the first orbit, 2 for the second orbit), - \( Z \) is the atomic number of the element. ### Step 3: Calculate the Radius for \( \text{He}^+ \) For \( \text{He}^+ \) (Helium with one electron), the atomic number \( Z = 2 \). - For the second orbit (\( n = 2 \)): \[ R_2(\text{He}^+) = \frac{0.53 \times 2^2}{2} = \frac{0.53 \times 4}{2} = \frac{2.12}{2} = 1.06 \, \text{Å} \] ### Step 4: Calculate the Radius for Hydrogen For hydrogen (\( Z = 1 \)): - For the first orbit (\( n = 1 \)): \[ R_1(\text{H}) = \frac{0.53 \times 1^2}{1} = 0.53 \, \text{Å} \] ### Step 5: Compare the Radii Now we compare the two results: - \( R_2(\text{He}^+) = 1.06 \, \text{Å} \) - \( R_1(\text{H}) = 0.53 \, \text{Å} \) Since \( 1.06 \, \text{Å} \) is not equal to \( 0.53 \, \text{Å} \), the assertion is **false**. ### Step 6: Analyze the Reason The reason states that the radius of an orbit in hydrogen-like species is directly proportional to \( n \) and inversely proportional to \( Z \). ### Step 7: Correct the Reason From the formula \( R_n = \frac{0.53 \, n^2}{Z} \): - The radius is directly proportional to \( n^2 \) (not \( n \)), and inversely proportional to \( Z \). Therefore, this statement is also **false**. ### Conclusion Both the assertion and the reason are false. ### Final Answer Both the assertion (A) and the reason (R) are false.
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