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Correct order of radii...

Correct order of radii

A

`Na gt Mg gt AI`

B

`Na^(+) gt Mg^(2+) gt AI^(3+)`

C

`I+ lt I lt I^(-)`

D

N , He, Ne

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correct order of radii for the given elements and ions, we need to analyze each option based on the principles of atomic and ionic radii. ### Step-by-Step Solution: 1. **Option 1: Sodium (Na), Magnesium (Mg), Aluminum (Al)** - These elements are in the same period (Period 3). - As we move from left to right across a period, the effective nuclear charge (Z_eff) increases because the number of protons increases while the shielding effect remains relatively constant. - This increase in Z_eff pulls the electrons closer to the nucleus, resulting in a decrease in atomic radius. - Therefore, the order of radii is: \[ \text{Na} > \text{Mg} > \text{Al} \] - **Conclusion for Option 1:** Correct order is Na > Mg > Al. 2. **Option 2: Na⁺, Mg²⁺, Al³⁺** - These ions are isoelectronic, meaning they have the same number of electrons (10 electrons). - However, they have different nuclear charges: Na⁺ has 11 protons, Mg²⁺ has 12 protons, and Al³⁺ has 13 protons. - As the positive charge increases, the ionic radius decreases due to the increased attraction between the nucleus and the electrons. - Therefore, the order of ionic radii is: \[ \text{Na}^+ > \text{Mg}^{2+} > \text{Al}^{3+} \] - **Conclusion for Option 2:** Correct order is Na⁺ > Mg²⁺ > Al³⁺. 3. **Option 3: I⁻, I, I⁺** - Here, we have anions and cations of iodine. - The ionic radius of an anion (I⁻) is larger than that of a neutral atom (I), which in turn is larger than that of a cation (I⁺). - Therefore, the order of radii is: \[ \text{I}^- > \text{I} > \text{I}^+ \] - **Conclusion for Option 3:** Correct order is I⁻ > I > I⁺. 4. **Option 4: Nitrogen (N), Helium (He), Neon (Ne)** - Helium and Neon are noble gases, and their radii are measured as Van der Waals radii. - As we move down a group, the atomic radius increases due to the addition of electron shells. - Thus, the order of radii is: \[ \text{He} < \text{N} < \text{Ne} \] - **Conclusion for Option 4:** Correct order is He < N < Ne. ### Final Summary of Correct Orders: - **Option 1:** Na > Mg > Al - **Option 2:** Na⁺ > Mg²⁺ > Al³⁺ - **Option 3:** I⁻ > I > I⁺ - **Option 4:** He < N < Ne
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