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Which ion has the largest radius ?...

Which ion has the largest radius ?

A

`Se^(2-) `

B

`F^(-)`

C

`O^(2-)`

D

`Rb^(+)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which ion has the largest radius among the given options (Se²⁻, F⁻, O²⁻, and Rb⁺), we can follow these steps: ### Step 1: Understand the Concept of Ionic Radius The ionic radius is influenced by the number of protons and electrons in an ion. Generally, as you move down a group in the periodic table, the ionic radius increases due to the addition of electron shells. Conversely, moving across a period from left to right typically leads to a decrease in ionic radius due to increased nuclear charge attracting the electrons more strongly. **Hint:** Remember that more protons in the nucleus lead to a stronger attraction to the electrons, which can decrease the size of the ion. ### Step 2: Identify the Ions and Their Electron Configurations - **Se²⁻ (Selenium)**: Atomic number 34, has gained 2 electrons (total 36 electrons). - **F⁻ (Fluoride)**: Atomic number 9, has gained 1 electron (total 10 electrons). - **O²⁻ (Oxide)**: Atomic number 8, has gained 2 electrons (total 10 electrons). - **Rb⁺ (Rubidium)**: Atomic number 37, has lost 1 electron (total 36 electrons). **Hint:** Write down the total number of electrons for each ion to compare their sizes effectively. ### Step 3: Compare the Positions in the Periodic Table - **Selenium (Se)** is in the 4th period and 16th group. - **Fluoride (F)** is in the 2nd period and 17th group. - **Oxide (O)** is in the 2nd period and 16th group. - **Rubidium (Rb)** is in the 5th period and 1st group. **Hint:** The position in the periodic table can give clues about the size; elements in lower periods generally have larger radii. ### Step 4: Analyze the Effective Nuclear Charge - For **Se²⁻**, with 34 protons and 36 electrons, the effective nuclear charge is relatively low, leading to a larger radius. - For **F⁻** and **O²⁻**, both have 9 and 8 protons respectively but have gained electrons, which leads to a smaller radius due to higher effective nuclear charge. - For **Rb⁺**, it has 37 protons and 36 electrons, which means it has a strong effective nuclear charge, leading to a smaller radius compared to Se²⁻. **Hint:** The effective nuclear charge is crucial in determining the size of the ion; the more protons compared to electrons, the smaller the ion tends to be. ### Step 5: Conclusion Based on the analysis, **Se²⁻** has the largest radius because it has the lowest effective nuclear charge among the ions considered, allowing for a larger size compared to the others. ### Final Answer **Se²⁻ (Selenium ion) has the largest radius.** ---
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