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In the following questions a statement o...

In the following questions a statement of assertion (A) is followed by a statement of reason ( R)
A: Ionization enthalpy decreases on moving down the group .
R: Force of attraction between nucleus and electrons decreases on moving down the group.

A

If Both Assertion & Reason are true and the reason is the correct explanation of the assertion then mark (1) .

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion then mark (2)

C

If Assertion is true statement but Reason is false then mark (3)

D

If both Assertion and Reason are false statements then mark (4)

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the given assertion (A) and reason (R), we will break down the concepts involved step by step. ### Step 1: Understanding Ionization Enthalpy - **Definition**: Ionization enthalpy (or ionization energy) is the amount of energy required to remove the outermost electron from an isolated gaseous atom. - **Importance**: A higher ionization enthalpy indicates that the outermost electron is held more tightly by the nucleus, while a lower ionization enthalpy suggests that the electron can be removed more easily. **Hint**: Remember that ionization enthalpy is related to how strongly the nucleus attracts the outermost electron. ### Step 2: Analyzing the Assertion - **Assertion (A)**: "Ionization enthalpy decreases on moving down the group." - **Explanation**: As we move down a group in the periodic table, the atomic size increases due to the addition of electron shells. This means that the outermost electrons are further away from the nucleus. **Hint**: Consider how the distance between the nucleus and the outermost electron affects the energy required to remove that electron. ### Step 3: Understanding the Reason - **Reason (R)**: "Force of attraction between nucleus and electrons decreases on moving down the group." - **Explanation**: As the atomic size increases, the distance between the nucleus and the outermost electron increases. This increased distance results in a weaker electrostatic attraction between the positively charged nucleus and the negatively charged outermost electron. **Hint**: Think about how distance affects the strength of the force of attraction between charged particles. ### Step 4: Connecting Assertion and Reason - The assertion states that ionization enthalpy decreases down the group, which is true because the outermost electrons are held less tightly due to increased distance from the nucleus. - The reason provided explains why this occurs: the force of attraction between the nucleus and the outermost electrons decreases as we move down the group. **Hint**: Check if the reason logically supports the assertion. ### Step 5: Conclusion - Both the assertion and reason are correct. - The reason provided is a valid explanation for the assertion. **Final Answer**: Both assertion (A) and reason (R) are correct, and the reason is the correct explanation for the assertion.
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