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In the following questions, a statement ...

In the following questions, a statement of assertion (A) is followed by a statement of reason (R )
A : H-F forms stronger hydrogen bond than `H_(2)` O.
R : F is more electronegative than oxygen.

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion, then mark (1)

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion, then mark (2)

C

If Assertion is true statement but Reason is false, then mark (3)

D

If both Assertion and Reason are false statements , then mark (4).

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the given assertion (A) and reason (R), we will break down the statements and evaluate their truthfulness and the relationship between them. ### Step 1: Evaluate the Assertion (A) **Assertion (A): H-F forms stronger hydrogen bonds than H2O.** - Hydrogen bonding occurs when a hydrogen atom is covalently bonded to a highly electronegative atom (like F, O, or N) and is attracted to another electronegative atom. - HF (hydrogen fluoride) does indeed form hydrogen bonds. However, H2O (water) is known for its strong hydrogen bonding capabilities due to its ability to form multiple hydrogen bonds. - In H2O, each molecule can form hydrogen bonds with four neighboring water molecules due to the two hydrogen atoms and two lone pairs on the oxygen atom. - In contrast, HF can only form hydrogen bonds with two other HF molecules. - Therefore, while HF does form hydrogen bonds, the assertion that HF forms stronger hydrogen bonds than H2O is **false**. ### Step 2: Evaluate the Reason (R) **Reason (R): F is more electronegative than oxygen.** - Electronegativity is a measure of the tendency of an atom to attract a bonding pair of electrons. - Fluorine (F) is indeed more electronegative than oxygen (O). The electronegativity values are approximately 4.0 for F and 3.5 for O on the Pauling scale. - This means that F has a stronger pull on the electrons in a bond compared to O. - Therefore, the reason that "F is more electronegative than oxygen" is **true**. ### Step 3: Analyze the Relationship Between A and R - The assertion states that HF forms stronger hydrogen bonds than H2O, which we found to be false. - The reason states that F is more electronegative than O, which is true. However, this does not directly support the assertion that HF forms stronger hydrogen bonds than H2O. - Thus, while both statements are true, the reason does not correctly explain the assertion. ### Conclusion - **Assertion (A)** is **false**. - **Reason (R)** is **true**. - Therefore, the correct answer is: **Assertion is false, but reason is true.** ### Final Answer The answer is option 3: Assertion is false but reason is true. ---
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