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A : For an isolated system Delta G = - ...

A : For an isolated system `Delta G = - TDeltaS_("total")`
R: For an isolated system q = 0.

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion , then mark (1)

B

If both Assertion & Reason are true and the reason is not the correct explanation of the assertion, then mark (2)

C

If Assertion is true statement but Reason is false, then mark (3)

D

If both Assertion is true statement but Reason is false, then mark (3)

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the assertion and the reason provided, and determine their validity and relationship. ### Step-by-Step Solution: 1. **Understanding the Assertion (A)**: - The assertion states: For an isolated system, \(\Delta G = -T \Delta S_{\text{total}}\). - In thermodynamics, for an isolated system, the total change in Gibbs free energy (\(\Delta G\)) is related to the total entropy change (\(\Delta S_{\text{total}}\)) of the system. This relationship holds true because, in an isolated system, energy and matter cannot be exchanged with the surroundings. 2. **Understanding the Reason (R)**: - The reason states: For an isolated system, \(q = 0\). - An isolated system is defined as one that does not exchange heat (\(q\)) or work (\(W\)) with its surroundings. Therefore, it is correct to say that \(q = 0\) in an isolated system. 3. **Analyzing the Relationship**: - The assertion is true because it correctly describes the relationship between Gibbs free energy and entropy in an isolated system. - The reason is also true because it accurately describes a characteristic of isolated systems. - However, the reason does not directly explain why the assertion is true. The assertion is a consequence of the definitions and relationships in thermodynamics, while the reason simply states a property of isolated systems. 4. **Conclusion**: - Both the assertion and reason are true, but the reason does not provide a correct explanation for the assertion. Therefore, the correct choice is that both are true, but the reason is not a correct explanation of the assertion. ### Final Answer: - The correct answer is: **Option B**: Both assertion and reason are true, but reason is incorrect explanation of assertion.
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