Home
Class 12
CHEMISTRY
The dissociation constant of a weak acid...

The dissociation constant of a weak acid HA and weak base BOH are `2 xx 10^(-5) and 5 xx 10^(-6)` respectively.
The equilibrium constant for the neutralization reaction of the two is (ignnore hydrolysis of resulting salt )

A

`1.0 xx 10^(-4)`

B

`1.0 xx 10^(-10)`

C

`2.5 xx 10^(-1)`

D

`1.0 xx 10^4`

Text Solution

AI Generated Solution

The correct Answer is:
To find the equilibrium constant for the neutralization reaction of a weak acid (HA) and a weak base (BOH), we can follow these steps: ### Step 1: Write the neutralization reaction The neutralization reaction between the weak acid HA and the weak base BOH can be represented as: \[ \text{HA} + \text{BOH} \rightleftharpoons \text{A}^- + \text{B}^+ + \text{H}_2\text{O} \] ### Step 2: Define the equilibrium constant expression The equilibrium constant \( K \) for this reaction can be expressed as: \[ K = \frac{[\text{A}^-][\text{B}^+]}{[\text{HA}][\text{BOH}]} \] ### Step 3: Relate \( K \) to \( K_a \) and \( K_b \) We know the dissociation constants for the weak acid and weak base: - \( K_a \) for HA: \[ K_a = \frac{[\text{H}^+][\text{A}^-]}{[\text{HA}]} \] - \( K_b \) for BOH: \[ K_b = \frac{[\text{B}^+][\text{OH}^-]}{[\text{BOH}]} \] ### Step 4: Use the ion product of water The ion product of water \( K_w \) is given by: \[ K_w = [\text{H}^+][\text{OH}^-] = 1 \times 10^{-14} \] ### Step 5: Relate \( K \) to \( K_a \) and \( K_b \) From the above expressions, we can derive the relationship: \[ K = \frac{K_a \cdot K_b}{K_w} \] ### Step 6: Substitute the values Given: - \( K_a = 2 \times 10^{-5} \) - \( K_b = 5 \times 10^{-6} \) - \( K_w = 1 \times 10^{-14} \) Substituting these values into the equation: \[ K = \frac{(2 \times 10^{-5}) \cdot (5 \times 10^{-6})}{1 \times 10^{-14}} \] ### Step 7: Calculate \( K \) Calculating the numerator: \[ (2 \times 5) = 10 \] And the powers of ten: \[ 10^{-5} \cdot 10^{-6} = 10^{-11} \] So, \[ K = \frac{10 \times 10^{-11}}{10^{-14}} = 10 \times 10^{3} = 1 \times 10^{4} \] ### Final Answer Thus, the equilibrium constant for the neutralization reaction is: \[ K = 1 \times 10^{4} \]
Promotional Banner

Topper's Solved these Questions

  • EQUILIBRIUM

    AAKASH INSTITUTE|Exercise ASSIGNMENT (SECTION -A)|50 Videos
  • EQUILIBRIUM

    AAKASH INSTITUTE|Exercise ASSIGNMENT (SECTION -B)|35 Videos
  • EQUILIBRIUM

    AAKASH INSTITUTE|Exercise Assignment (SECTION-J) (AAKASH CHALLENGERS QUESTIONS)|6 Videos
  • ENVIRONMENTAL CHEMISTRY

    AAKASH INSTITUTE|Exercise ASSIGNMENT (SECTION-D) (Assertion - Reason Type Questions)|5 Videos
  • GENERAL PRINCIPLES AND PROCESSES OF ISOLATION OF ELEMENTS

    AAKASH INSTITUTE|Exercise Assignment (Section-D) Assertion-Reason Type Question|15 Videos

Similar Questions

Explore conceptually related problems

The rate constans of forward and backward reactions are 8.5 xx 10^(-5) and 2.38 xx 10^(-4) respectively. The equilibrium constant if

The first and second dissociation constants of an acid H_(2)A are 1 xx 10^(-5) and 5 xx 10^(-10) respectively. The overall dissociation constant of the acid will be

The dissociation constant of two acids HA_(1) and HA_(2) are 4.5 xx 10^(-4) and 1.8 xx 10^(-5) respectively. If both are having equal concentrations the relative strength of acids is

The dissociation constants of two acids HA_(1) and HA_(2) are 3.0xx10^(-4) and 1.8xx10^(-5) respectively. The relative strengths of the acids will be approximately

AAKASH INSTITUTE-EQUILIBRIUM-EXERCISE
  1. In which of the following case pH is greater than 7 ?

    Text Solution

    |

  2. The compound that is not a Lewis acid

    Text Solution

    |

  3. The pH of a solution obtained by mixing 100 ml of 0.2 M CH3COOH with 1...

    Text Solution

    |

  4. With increases in temperature pH of pure water

    Text Solution

    |

  5. The pH of a solution increased from 3 to 6. Its [H^(o+)] will be

    Text Solution

    |

  6. Which pair will show common ion effect ?

    Text Solution

    |

  7. The pH of solution at 25^@C which has twice as many hydroxide ion as i...

    Text Solution

    |

  8. Fear or exitement, generally cause one to breathe rapidaly and it resu...

    Text Solution

    |

  9. Which of the following can act as a lewis acid ?

    Text Solution

    |

  10. Which of the following is an Arrhenius base ?

    Text Solution

    |

  11. For a MX2 type salt if K(sp) is solubility product, then solubility ...

    Text Solution

    |

  12. The compound whose 0.1 M solution is basic is

    Text Solution

    |

  13. The correct order of increasing solubility of AgCI in (A) water (B...

    Text Solution

    |

  14. The solubility of AgCI is

    Text Solution

    |

  15. If the Kb value in the hydrolysis reaction B^(+)+H2O hArr BOH +H^+ ...

    Text Solution

    |

  16. Which of the following increasing order of pH of 0.1 M solution of the...

    Text Solution

    |

  17. The dissociation constant of a weak acid HA and weak base BOH are 2 x...

    Text Solution

    |

  18. K(sp) of Mg(OH)2 is 4.0 xx 10^(-12). The number of moles of moles of M...

    Text Solution

    |

  19. If the solubility of AI2(SO4) is S , then its solubility product is

    Text Solution

    |

  20. Which of the following is correct for the solution of the salt of weak...

    Text Solution

    |