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The pH of M/(100) Ca(OH)2 is...

The pH of `M/(100) Ca(OH)_2` is

A

1.699

B

12

C

12.301

D

12.699

Text Solution

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The correct Answer is:
To find the pH of a \( M/(100) \) solution of \( Ca(OH)_2 \), we can follow these steps: ### Step 1: Determine the concentration of \( Ca(OH)_2 \) Given that the concentration is \( M/(100) \), we can express this as: \[ \text{Concentration of } Ca(OH)_2 = \frac{1}{100} \, M = 10^{-2} \, M \] ### Step 2: Calculate the concentration of hydroxide ions \( OH^- \) Calcium hydroxide dissociates in water as follows: \[ Ca(OH)_2 \rightarrow Ca^{2+} + 2OH^- \] From the dissociation, we see that 1 mole of \( Ca(OH)_2 \) produces 2 moles of \( OH^- \). Therefore, the concentration of hydroxide ions will be: \[ [OH^-] = 2 \times [Ca(OH)_2] = 2 \times 10^{-2} \, M = 2 \times 10^{-2} \, M \] ### Step 3: Calculate the pOH The pOH can be calculated using the formula: \[ pOH = -\log[OH^-] \] Substituting the concentration of hydroxide ions: \[ pOH = -\log(2 \times 10^{-2}) \] ### Step 4: Calculate the logarithm To calculate \( -\log(2 \times 10^{-2}) \): \[ pOH = -(\log(2) + \log(10^{-2})) = -(\log(2) - 2) \] Using \( \log(2) \approx 0.301 \): \[ pOH = -(0.301 - 2) = 1.699 \] ### Step 5: Calculate the pH Using the relationship between pH and pOH: \[ pH + pOH = 14 \] We can rearrange this to find pH: \[ pH = 14 - pOH = 14 - 1.699 = 12.301 \] ### Final Answer Therefore, the pH of the \( M/(100) \) solution of \( Ca(OH)_2 \) is approximately: \[ \text{pH} \approx 12.301 \] ---
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