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If alpha is degree of dissocliation, the...

If `alpha` is degree of dissocliation, then the total number of moles for the reaction starting with 1 mole of HI `2HI= H_2 +I_2` will be

A

1

B

`1-alpha`

C

2

D

`2-alpha`

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The correct Answer is:
To solve the problem, we need to determine the total number of moles at equilibrium for the reaction: \[ 2 \text{HI} \rightleftharpoons \text{H}_2 + \text{I}_2 \] starting with 1 mole of HI and given that the degree of dissociation is represented by \( \alpha \). ### Step-by-Step Solution: 1. **Initial Moles**: - Initially, we have 1 mole of HI, and no moles of H2 or I2. - Therefore, the initial amounts can be represented as: - \[\text{HI} = 1 \text{ mole}\] - \[\text{H}_2 = 0 \text{ moles}\] - \[\text{I}_2 = 0 \text{ moles}\] 2. **Degree of Dissociation**: - The degree of dissociation \( \alpha \) indicates the fraction of the initial moles of HI that dissociate. - For the reaction \( 2 \text{HI} \rightarrow \text{H}_2 + \text{I}_2 \), if \( \alpha \) is the degree of dissociation, then: - Moles of HI dissociated = \( 2\alpha \) - Moles of H2 formed = \( \alpha \) - Moles of I2 formed = \( \alpha \) 3. **Moles at Equilibrium**: - After dissociation, the moles of each species will be: - Moles of HI remaining = \( 1 - 2\alpha \) - Moles of H2 = \( \alpha \) - Moles of I2 = \( \alpha \) 4. **Total Moles at Equilibrium**: - To find the total number of moles at equilibrium, we sum the moles of all species: \[ \text{Total moles} = (\text{Moles of HI remaining}) + (\text{Moles of H2}) + (\text{Moles of I2}) \] \[ \text{Total moles} = (1 - 2\alpha) + \alpha + \alpha \] \[ \text{Total moles} = 1 - 2\alpha + 2\alpha \] \[ \text{Total moles} = 1 \] ### Conclusion: The total number of moles at equilibrium is **1 mole**.
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