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A: The reaction 2NO(g) +O2(g) hArr 2NO2(...

A: The reaction `2NO(g) +O_2(g) hArr 2NO_2(g)` is
favoured in the forward direction with increase of pressure.
R : The above reaction is exothermic .

A

If both Assertion & Reason are true and the reason in the corret explanation of the assertion, then mark

B

If both assertion & Reason are true but the reason is not the correct explanation of the assertion, then mark

C

If Assertion is true statement but Reason is false then mark

D

If both Assertion and Reason are false statements , then mark

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the statements given: **Statement A:** The reaction `2NO(g) + O2(g) ⇌ 2NO2(g)` is favored in the forward direction with an increase in pressure. **Statement R:** The above reaction is exothermic. ### Step-by-Step Solution: 1. **Understanding the Reaction:** - The balanced chemical equation is `2NO(g) + O2(g) ⇌ 2NO2(g)`. - On the left side (reactants), we have 3 moles of gas (2 moles of NO and 1 mole of O2). - On the right side (products), we have 2 moles of gas (2 moles of NO2). 2. **Applying Le Chatelier's Principle:** - According to Le Chatelier's Principle, if we increase the pressure in a system at equilibrium, the equilibrium will shift towards the side with fewer moles of gas to minimize the change in pressure. - In this case, the forward reaction produces 2 moles of NO2 from 3 moles of reactants. Therefore, increasing the pressure will favor the formation of NO2, which means the equilibrium will shift to the right. 3. **Evaluating Statement A:** - Since the forward reaction (producing NO2) is favored with an increase in pressure, Statement A is **correct**. 4. **Determining if the Reaction is Exothermic:** - The reaction involves the formation of NO2 from NO and O2. In combustion reactions, energy is typically released, indicating that the reaction is exothermic. - If the reaction is exothermic, the enthalpy change (ΔH) is negative, which aligns with the idea that heat is released during the reaction. 5. **Evaluating Statement R:** - Since the formation of NO2 from NO and O2 is indeed exothermic, Statement R is also **correct**. 6. **Conclusion:** - Both statements A and R are correct. However, the relationship between the two statements is not direct; the effect of pressure is independent of whether the reaction is exothermic or endothermic. ### Final Answer: Both statements A and R are correct, but they are not directly related.
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