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A mixture of two liquids A and B having ...

A mixture of two liquids A and B having boiling points of A is `70^@C` and boiling point of B is `100^@C` distills at `101.2^@C` as single liquid, hence this mixture is

A

Ideal solution

B

Non ideal solution showing +ve deviation

C

Non ideal solution showing -ve deviation

D

Immiscible solution

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the information given about the mixture of two liquids A and B, their boiling points, and the boiling point of the mixture. ### Step-by-Step Solution: 1. **Identify the Boiling Points:** - The boiling point of liquid A is given as 70°C. - The boiling point of liquid B is given as 100°C. - The boiling point of the mixture is given as 101.2°C. 2. **Compare the Boiling Point of the Mixture with Individual Components:** - The boiling point of the mixture (101.2°C) is higher than the boiling points of both A (70°C) and B (100°C). - This indicates that the mixture does not behave ideally. 3. **Understand the Implications of the Boiling Point:** - Since the boiling point of the mixture is higher than both pure components, it suggests that the vapor pressure of the mixture is lower than that of the individual components. - This is indicative of a non-ideal solution. 4. **Determine the Type of Non-Ideal Solution:** - In non-ideal solutions, if the boiling point of the mixture is higher than that of the individual components, it indicates a negative deviation from Raoult's law. - Negative deviation occurs due to strong intermolecular forces (adhesive forces) between the components of the mixture, which leads to a lower vapor pressure. 5. **Conclusion:** - Therefore, the mixture of liquids A and B is classified as a non-ideal solution showing negative deviation. ### Final Answer: The mixture is a non-ideal solution showing negative deviation.
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