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Which relation is correct?...

Which relation is correct?

A

Molar conductance = conductivity `xx` concentration

B

Equivalent conductance `= ("Conductivity")/("Volume")`

C

Cell constant `=("Conductivity")/("Conductance")`

D

Conductance = specific conductivity `xx` cell constant

Text Solution

AI Generated Solution

The correct Answer is:
To determine which relation is correct among the given options, we will analyze each of the provided statements step by step. ### Step 1: Understanding Conductance and Resistance - Conductance (G) is the reciprocal of resistance (R), given by the formula: \[ G = \frac{1}{R} \] - Resistance is related to the dimensions of the conductor: \[ R = \frac{l}{A \cdot \sigma} \] where \( l \) is the length, \( A \) is the area of cross-section, and \( \sigma \) is the conductivity. ### Step 2: Relating Conductivity and Conductance - The conductivity (k) can be expressed in terms of conductance (G) and the cell constant (C): \[ k = G \cdot C \] where the cell constant \( C \) is defined as: \[ C = \frac{l}{A} \] ### Step 3: Analyzing the Options 1. **Option A**: Molar conductance \( \Lambda_m = k \cdot C \) - This is incorrect. The correct relation is: \[ \Lambda_m = \frac{k}{c} \] where \( c \) is the concentration. 2. **Option B**: Equivalent conductance \( \Lambda_{eq} = k \cdot V \) - This is also incorrect. The correct relation is: \[ \Lambda_{eq} = \frac{k \cdot 1000}{N} \] where \( N \) is the normality. 3. **Option C**: Cell constant \( C = \frac{k}{G} \) - This is correct as derived from the relation \( k = G \cdot C \). 4. **Option D**: Conductance \( G = k \cdot C \) - This is incorrect as it confuses the definitions. ### Conclusion The only correct relation among the options given is: \[ \text{Option C: Cell constant } C = \frac{k}{G} \]
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