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The specific conductivity of 0.5N soluti...

The specific conductivity of 0.5N solution is `0.01287 ohm^(-1) cm^(-1)`. What would be its equivalent conductance?

A

257.4

B

2.574

C

25.74

D

`0.2574 ohm^(-1) cm^(2) (g.eq)^(-1)`

Text Solution

AI Generated Solution

The correct Answer is:
To find the equivalent conductance of a 0.5N solution with a specific conductivity of \(0.01287 \, \text{ohm}^{-1} \text{cm}^{-1}\), we can use the formula for equivalent conductance (\(\Lambda_e\)): \[ \Lambda_e = \frac{\kappa \times 1000}{N} \] Where: - \(\Lambda_e\) = equivalent conductance (in \(\text{ohm}^{-1} \text{cm}^2 \text{eq}^{-1}\)) - \(\kappa\) = specific conductivity (in \(\text{ohm}^{-1} \text{cm}^{-1}\)) - \(N\) = normality of the solution (in eq/L) ### Step-by-step Solution: 1. **Identify the given values**: - Specific conductivity (\(\kappa\)) = \(0.01287 \, \text{ohm}^{-1} \text{cm}^{-1}\) - Normality (N) = \(0.5 \, \text{N}\) 2. **Substitute the values into the formula**: \[ \Lambda_e = \frac{0.01287 \times 1000}{0.5} \] 3. **Calculate the numerator**: \[ 0.01287 \times 1000 = 12.87 \] 4. **Divide by normality**: \[ \Lambda_e = \frac{12.87}{0.5} = 25.74 \] 5. **Final result**: \[ \Lambda_e = 25.74 \, \text{ohm}^{-1} \text{cm}^2 \text{eq}^{-1} \] ### Conclusion: The equivalent conductance of the 0.5N solution is \(25.74 \, \text{ohm}^{-1} \text{cm}^2 \text{eq}^{-1}\). ---
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