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Which of the following is the correct st...

Which of the following is the correct statement ?

A

Hydrogen has the same I.E. as that of alkali metals

B

Hydrogen has strong tendency to gain one electron same as that of alkali metals

C

Hydrogen molecules is diatomic so are the halogens

D

Electron affinity of hydrogen is same as that of halogens

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the statements provided is correct, we will analyze each option step by step. ### Step 1: Analyze Option 1 **Statement**: Hydrogen has the same ionization energy as alkali metals. **Analysis**: - Hydrogen has an atomic number of 1 and possesses only one electron. - This electron is strongly attracted to the nucleus due to the small size of the hydrogen atom. - Alkali metals, on the other hand, have larger atomic sizes and their outermost electron is further from the nucleus, leading to lower ionization energy. - Therefore, more energy is required to remove the electron from hydrogen than from alkali metals. **Conclusion**: Option 1 is **incorrect**. ### Step 2: Analyze Option 2 **Statement**: Hydrogen has a stronger tendency to gain one electron, similar to alkali metals. **Analysis**: - Alkali metals typically lose one electron to achieve a noble gas configuration. - Hydrogen, however, tends to gain one electron to achieve the helium configuration (1s²). - Thus, hydrogen's behavior is more similar to that of halogens, which gain electrons, rather than alkali metals. **Conclusion**: Option 2 is **incorrect**. ### Step 3: Analyze Option 3 **Statement**: Hydrogen molecule is diatomic, as are the halogens. **Analysis**: - Diatomic molecules consist of two atoms. - Hydrogen exists as H₂, which is indeed a diatomic molecule. - Halogens also exist as diatomic molecules (e.g., Cl₂, F₂, I₂). - Both hydrogen and halogens are homonuclear diatomic molecules, meaning they are composed of two atoms of the same element. **Conclusion**: Option 3 is **correct**. ### Step 4: Analyze Option 4 **Statement**: The electro affinity of hydrogen is the same as that of halogens. **Analysis**: - The electro affinity of hydrogen is positive (approximately +72.8 kJ/mol), indicating that energy is required to add an electron. - In contrast, halogens have a negative electro affinity, meaning they release energy when gaining an electron. - Therefore, the electro affinity values of hydrogen and halogens are not the same. **Conclusion**: Option 4 is **incorrect**. ### Final Answer The correct statement is **Option 3**: Hydrogen molecule is diatomic, as are the halogens. ---
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