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A : Complete hydrolysis of one mole of p...

A : Complete hydrolysis of one mole of peroxydi-sulphuric acid gives one omle of `H_2O_2` and 2 mole `H_2SO_4`.
R : Peroxydisulphuric acid has zero peroxy lingage.

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion, then mark (1)

B

If both Assertion & Reason are true but the reason is not the correct explanantion of the assertion, then mark (2)

C

If assertion is true statements but Reason is false, then mark (3)

D

If both Assertion and Reason are false statements, then mark (4)

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the assertion and reason provided regarding peroxydisulphuric acid (H2S2O8). ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that the complete hydrolysis of one mole of peroxydisulphuric acid (H2S2O8) yields one mole of hydrogen peroxide (H2O2) and two moles of sulfuric acid (H2SO4). - The molecular formula of peroxydisulphuric acid is H2S2O8, which contains a peroxy linkage (–O–O–). 2. **Chemical Reaction**: - When peroxydisulphuric acid undergoes hydrolysis, it reacts with water (H2O). - The reaction can be represented as follows: \[ H2S2O8 + H2O \rightarrow H2O2 + 2 H2SO4 \] - This indicates that one mole of peroxydisulphuric acid produces one mole of hydrogen peroxide and two moles of sulfuric acid. 3. **Verification of the Assertion**: - The assertion is correct as the hydrolysis of peroxydisulphuric acid indeed yields 1 mole of H2O2 and 2 moles of H2SO4. 4. **Understanding the Reason**: - The reason states that peroxydisulphuric acid has zero peroxy linkage. - However, peroxydisulphuric acid contains a peroxy linkage (–O–O–), which is a characteristic feature of compounds that contain peroxy groups. 5. **Verification of the Reason**: - The reason is incorrect because peroxydisulphuric acid does have a peroxy linkage, contrary to what is stated. 6. **Conclusion**: - The assertion is true, while the reason is false. Therefore, the correct option is that the assertion is true, but the reason is false. ### Final Answer: - Assertion (A) is true, and Reason (R) is false.
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