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A : CaCO(3) requires more temperature th...

A : `CaCO_(3)` requires more temperature than `MgCO_(3)` for decomposition.
R : Group II metal carbonates on decomposition gives respective oxide and `CO_(2)`

A

If both Assertion & Reason are true and the reason is the correct explanantion of the assertion, then mark (1).

B

If both Assertion & Reason are true and the reason is the correct explanantion of the assertion, then mark (2).

C

If Assertion is true statement but Reason is false. Them mark (3).

D

If both Assertion and reason are false statement, then mark (4).

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the assertion and reason given in the question step by step. ### Step 1: Analyze the Assertion The assertion states that "CaCO₃ requires more temperature than MgCO₃ for decomposition." - **Decomposition of Carbonates**: When metal carbonates decompose, they form metal oxides and carbon dioxide. - **Reactions**: - For Calcium Carbonate: \[ \text{CaCO}_3 \rightarrow \text{CaO} + \text{CO}_2 \] - For Magnesium Carbonate: \[ \text{MgCO}_3 \rightarrow \text{MgO} + \text{CO}_2 \] ### Step 2: Compare the Stability of Carbonates The stability of metal carbonates generally decreases down the group in the periodic table. - **Group II Carbonates**: As we move down the group from magnesium to calcium, the size of the metal ion increases, and the electropositive character increases. This leads to a stronger bond between the carbonate ion and the metal ion in calcium carbonate compared to magnesium carbonate. - **Bond Strength**: The bond strength in CaCO₃ is greater than that in MgCO₃ due to the higher electropositive character of calcium compared to magnesium. ### Step 3: Conclusion for Assertion Since CaCO₃ has a stronger bond and is more stable than MgCO₃, it requires more energy (higher temperature) to decompose. Therefore, the assertion is **true**. ### Step 4: Analyze the Reason The reason states that "Group II metal carbonates on decomposition give respective oxide and CO₂." - This statement is generally true as it describes the decomposition products of group II metal carbonates. ### Step 5: Check if the Reason Explains the Assertion While the reason is true, it does not explain why CaCO₃ requires more temperature than MgCO₃ for decomposition. The reason simply states the products of decomposition without addressing the energy required for the decomposition process. ### Final Conclusion - **Assertion**: True - **Reason**: True, but does not explain the assertion. ### Answer Options Based on the analysis, the correct option is: - **Option 2**: Both assertion and reason are true, but the reason is not the correct explanation of the assertion.
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