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Select the incorrect statement for B(2) ...

Select the incorrect statement for `B_(2) H_(6)`

A

It contains B- B ionic bonds

B

Each boron is `sp^(3)` hybridised

C

It has two types of hydrogen bonds

D

All of these

Text Solution

AI Generated Solution

The correct Answer is:
To determine the incorrect statement regarding diborane (B₂H₆), we will analyze the properties and structure of diborane step by step. ### Step 1: Understand the Structure of Diborane (B₂H₆) Diborane consists of two boron atoms and six hydrogen atoms. The structure can be visualized as follows: - Each boron atom is bonded to three hydrogen atoms. - There are two bridging hydrogen atoms that connect the two boron atoms. ### Step 2: Analyze the Bonding in Diborane In diborane, the bonding involves: - **Terminal Bonds**: Each boron atom forms two terminal covalent bonds with two hydrogen atoms. - **Bridge Bonds**: The two boron atoms are connected by two bridging hydrogen atoms, which are not considered as typical covalent bonds but rather as bridge bonds. ### Step 3: Evaluate the Statements Now, let's evaluate the statements provided: 1. **Statement 1**: "It contains B-B ionic bond." - **Analysis**: This statement is incorrect because there is no direct B-B bond in diborane. The boron atoms are connected through hydrogen atoms, which act as a bridge. Therefore, this statement is false. 2. **Statement 2**: "Each boron is sp³ hybridized." - **Analysis**: This statement is correct. Each boron atom undergoes sp³ hybridization due to the presence of four equivalent bonds (three with hydrogen and one bridge bond). 3. **Statement 3**: "It has two types of hydrogen bonds." - **Analysis**: This statement is correct. Diborane has two types of hydrogen bonding: terminal covalent bonds and bridging hydrogen bonds. 4. **Statement 4**: "All of the above statements are correct." - **Analysis**: This statement is incorrect because we have already identified that Statement 1 is incorrect. ### Conclusion The incorrect statement regarding diborane (B₂H₆) is **Statement 1**, which claims that it contains a B-B ionic bond.
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