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The shape of Cl F(2)^(-) , is...

The shape of `Cl F_(2)^(-)` , is

A

Linear

B

Trigonal bipyramidal

C

Square pyramidal

D

T -shape

Text Solution

AI Generated Solution

The correct Answer is:
To determine the shape of the ClF₂⁻ ion, we can follow these steps: ### Step 1: Determine the Valence Electrons - Chlorine (Cl) has 7 valence electrons. - Each Fluorine (F) atom has 7 valence electrons, and there are 2 F atoms, contributing a total of 14 electrons. - Since the ion has a negative charge (−1), we add 1 more electron. **Calculation:** - Total valence electrons = 7 (from Cl) + 14 (from 2 F) + 1 (from the negative charge) = 22 valence electrons. ### Step 2: Determine the Central Atom and Electron Pairs - Chlorine is the central atom. - The total number of electron pairs can be calculated by dividing the total valence electrons by 2 (since each pair consists of 2 electrons). **Calculation:** - Total electron pairs = 22 valence electrons / 2 = 11 electron pairs. ### Step 3: Identify Bonding and Lone Pairs - ClF₂⁻ has 2 bonding pairs (from the two Cl-F bonds). - The remaining electron pairs will be lone pairs. **Calculation:** - Total pairs = 11 - Bonding pairs = 2 (from 2 Cl-F bonds) - Lone pairs = 11 - 2 = 9 lone pairs. ### Step 4: Determine Hybridization - The hybridization can be determined based on the number of electron pairs around the central atom. - With 11 electron pairs, the hybridization will be sp³d² (since it involves 5 orbitals). ### Step 5: Determine the Shape - The arrangement of the electron pairs will dictate the molecular geometry. - With 2 bonding pairs and 9 lone pairs, the shape will be influenced primarily by the positions of the bonding pairs. **Conclusion:** - The shape of ClF₂⁻ is T-shaped due to the presence of 2 bonding pairs and 3 lone pairs occupying the equatorial positions. ### Final Answer: The shape of ClF₂⁻ is T-shaped. ---
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