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A : All the oxides of boron family with ...

A : All the oxides of boron family with the general formula `M_(2) O_(3)` are basic .
R : From `B_(2) O_(3)` to `Tl_(2) O_(3)` basic character decreases .

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion , then mark (1)

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion , then mark (2)

C

If Assertion is true statement but Reason is false , then mark (3)

D

If both Assertion and Reason are false statements , then mark (4)

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the assertion and reason provided in the question, let's break it down step by step. ### Step 1: Understanding the Assertion - **Assertion (A)** states that all the oxides of the boron family with the general formula \( M_2O_3 \) are basic. - The boron family consists of elements such as Boron (B), Aluminium (Al), Gallium (Ga), Indium (In), and Thallium (Tl). - The general formula \( M_2O_3 \) indicates that these oxides are formed by these elements reacting with oxygen. ### Step 2: Evaluating the Basicity of Oxides - Basicity refers to the ability of an oxide to react with acids to form salts and water. - In the case of the boron family, as we move from Boron to Thallium, the metallic character increases, which generally leads to an increase in basicity. - Boron oxide (\( B_2O_3 \)) is amphoteric (can act as both an acid and a base), while Aluminium oxide (\( Al_2O_3 \)) is more basic, and the basicity continues to increase down the group. ### Step 3: Understanding the Reason - **Reason (R)** states that from \( B_2O_3 \) to \( Tl_2O_3 \), the basic character decreases. - This statement is incorrect because, as we move down the group from Boron to Thallium, the basic character actually increases due to the increasing metallic character. ### Step 4: Conclusion - The assertion is correct: all the oxides of the boron family with the general formula \( M_2O_3 \) are basic. - The reason is incorrect: the basic character does not decrease from \( B_2O_3 \) to \( Tl_2O_3 \); it actually increases. ### Final Answer - The assertion (A) is true, and the reason (R) is false. Therefore, the correct conclusion is that the assertion is correct, but the reason is not. ---
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