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A : Carbon has maximum tendency of caten...

A : Carbon has maximum tendency of catenation among group 14 .
R : C- C bond strength is very strong .

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion , then mark (1)

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion , then mark (2)

C

If Assertion is true statement but Reason is false , then mark (3)

D

If both Assertion and Reason are false statements , then mark (4)

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the given statements regarding carbon's catenation tendency and the strength of the C-C bond, we can break down the solution into the following steps: ### Step 1: Understand Catenation Catenation is defined as the ability of an element to form covalent bonds with itself, resulting in the formation of chains, rings, or cage structures. **Hint:** Remember that catenation involves the self-bonding of an element. ### Step 2: Identify Group 14 Elements Group 14 elements include Carbon (C), Silicon (Si), Germanium (Ge), Tin (Sn), and Lead (Pb). Among these, we need to focus on carbon's unique properties. **Hint:** List the elements of Group 14 to visualize the comparison. ### Step 3: Analyze Carbon's Catenation Tendency Carbon has the highest tendency for catenation in Group 14. This is due to several factors: - Carbon has a small atomic size, which allows for effective overlap of its orbitals. - Carbon has four valence electrons, enabling it to form four covalent bonds (tetravalency). **Hint:** Consider how atomic size and valency contribute to an element's bonding capabilities. ### Step 4: Discuss C-C Bond Strength The strength of the C-C bond is significant because it results from the effective overlapping of 2p orbitals. This strong bond energy contributes to the stability of carbon chains and structures. **Hint:** Think about how orbital overlap affects bond strength. ### Step 5: Compare with Other Group 14 Elements As we move down the group from carbon to lead, the atomic size increases, leading to less effective orbital overlap (e.g., 3p-3p in silicon). This results in a decreased tendency for catenation in heavier elements. **Hint:** Reflect on how increasing atomic size impacts bonding and catenation. ### Step 6: Conclusion Both the assertion (A) that carbon has the maximum tendency for catenation among Group 14 elements and the reason (R) that the C-C bond strength is very strong are true. The reason provided effectively explains the assertion. **Hint:** Ensure you can justify both statements with the concepts discussed. ### Final Answer Both the assertion and reason are true, and the reason is the correct explanation for the assertion.
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