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A : Cl(2) on reaction with NaOH (cold an...

A : `Cl_(2)` on reaction with NaOH (cold and dilute) gives `NaClO_(3)` .
R : `Cl_(2)` get oxidized only in this reaction .

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion , then mark (1)

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion , then mark (2)

C

If Assertion is true statement but Reason is false , then mark (3)

D

If both Assertion and Reason are false statements , then mark (4)

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided. **Assertion (A):** Cl₂ on reaction with NaOH (cold and dilute) gives NaClO₃. **Reason (R):** Cl₂ gets oxidized only in this reaction. ### Step-by-Step Solution: 1. **Understanding the Reaction:** - When chlorine gas (Cl₂) reacts with sodium hydroxide (NaOH) under cold and dilute conditions, it does not produce sodium chlorate (NaClO₃). Instead, it forms sodium chloride (NaCl) and sodium hypochlorite (NaOCl) as products. The balanced chemical equation for this reaction is: \[ Cl_2 + 2NaOH \rightarrow NaCl + NaOCl + H_2O \] 2. **Analyzing the Assertion:** - Since the assertion states that Cl₂ reacts with NaOH to give NaClO₃, and we have established that the products are NaCl and NaOCl, the assertion is **false**. 3. **Understanding Oxidation States:** - In the reaction, the oxidation state of chlorine in Cl₂ is 0. In NaCl, the oxidation state of Cl is -1, and in NaOCl, the oxidation state of Cl is +1. - This indicates that chlorine undergoes both oxidation (from 0 to +1 in NaOCl) and reduction (from 0 to -1 in NaCl) in this reaction. 4. **Analyzing the Reason:** - The reason states that Cl₂ gets oxidized only in this reaction. However, since Cl₂ is both oxidized and reduced in this reaction, the reason is also **false**. 5. **Conclusion:** - Both the assertion and the reason are false. Therefore, the correct answer is option 4: "Both statements are false."
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