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A : CN^(-) is pseudohalide . R : (CN)(...

A : `CN^(-)` is pseudohalide .
R : `(CN)_(2)` is pseudohalogen .

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion , then mark (1)

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion , then mark (2)

C

If Assertion is true statement but Reason is false , then mark (3)

D

If both Assertion and Reason are false statements , then mark (4)

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correctness of the assertion and reasoning provided in the question, we will analyze both statements step by step. ### Step 1: Analyze the Assertion **Assertion (A):** CN⁻ is a pseudohalide. 1. **Definition of Pseudohalide:** A pseudohalide is an anion that behaves similarly to halides. It typically has a negative charge and can form a hydra-acid with hydrogen and an insoluble salt with silver. 2. **Cyanide Ion (CN⁻):** The cyanide ion has a single negative charge. When it reacts with hydrogen (H⁺), it forms hydrocyanic acid (HCN), which is a hydra-acid. Additionally, when it reacts with silver (Ag⁺), it forms silver cyanide (AgCN), which is insoluble in water. 3. **Conclusion for Assertion:** Since CN⁻ meets the criteria of a pseudohalide, the assertion is true. ### Step 2: Analyze the Reasoning **Reason (R):** (CN)₂ is a pseudohalogen. 1. **Definition of Pseudohalogen:** A pseudohalogen is a compound that behaves like a halogen, typically being a dimer of a pseudohalide. 2. **Dimer of Cyanide:** The dimer of the cyanide ion (CN⁻) is (CN)₂, which can be represented as two cyanide ions bonded together. 3. **Conclusion for Reasoning:** Since (CN)₂ is indeed a dimer of the pseudohalide CN⁻, it qualifies as a pseudohalogen. Therefore, the reasoning is also true. ### Step 3: Evaluate the Relationship Between Assertion and Reasoning 1. **Correctness of Both Statements:** Both the assertion and reasoning are true. 2. **Explanation Validity:** However, the reasoning does not provide a correct explanation for the assertion. The assertion stands on its own based on the properties of CN⁻, while the reasoning simply states that (CN)₂ is a pseudohalogen without explaining why CN⁻ is a pseudohalide. ### Final Conclusion - **Both Assertion and Reasoning are true, but the Reasoning is not a correct explanation of the Assertion.** - Therefore, the correct answer is **Option 2**: Both assertion and reasoning are true, but the reason is not the correct explanation of the assertion. ---
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