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When molten NaCl is electrolysed by usin...

When molten NaCl is electrolysed by using inert electrode, the product obtained al cathode is

A

Na

B

`Cl_2`

C

`H_2`

D

Na Hg amalgam

Text Solution

AI Generated Solution

The correct Answer is:
To determine the product obtained at the cathode when molten NaCl is electrolyzed using inert electrodes, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding Electrolysis of Molten NaCl**: - When sodium chloride (NaCl) is molten, it dissociates into its ions: Na⁺ (sodium ions) and Cl⁻ (chloride ions). 2. **Setting Up the Electrolysis**: - In the electrolysis setup, we have an anode (positive electrode) and a cathode (negative electrode) connected to a power source. 3. **Identifying the Reactions**: - At the cathode, reduction occurs (gain of electrons). The possible ions that can be reduced are Na⁺ and Cl⁻. - Na⁺ can gain an electron to become sodium metal (Na), while Cl⁻ can be oxidized to form chlorine gas (Cl₂) at the anode. 4. **Reduction Reaction at the Cathode**: - The reduction reaction at the cathode can be represented as: \[ \text{Na}^+ + e^- \rightarrow \text{Na (s)} \] - This means that sodium ions (Na⁺) gain electrons and are reduced to solid sodium (Na). 5. **Conclusion**: - Therefore, the product obtained at the cathode during the electrolysis of molten NaCl is solid sodium (Na). ### Final Answer: The product obtained at the cathode when molten NaCl is electrolyzed is solid sodium (Na). ---
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