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K(2)Cr(2)O(7), + l^(-) + H^(+ )to Oxidiz...

`K_(2)Cr_(2)O_(7), + l^(-) + H^(+ )to` Oxidized product. The product is

A

`KIO_(3)`

B

`I_(2)`

C

`I_(3)^(-)`

D

`Cr_(2)O_(3)`

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The correct Answer is:
To determine the oxidized product from the reaction of potassium dichromate (K₂Cr₂O₇) with iodide ions (I⁻) in the presence of acid (H⁺), we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: The reactants in this reaction are potassium dichromate (K₂Cr₂O₇), iodide ions (I⁻), and hydrogen ions (H⁺) from the acid. 2. **Write the Reaction**: The reaction can be represented as: \[ K_2Cr_2O_7 + I^- + H^+ \rightarrow \text{Oxidized Product} \] 3. **Determine the Role of Each Species**: - Potassium dichromate (K₂Cr₂O₇) acts as an oxidizing agent. - Iodide ions (I⁻) will be oxidized to iodine (I₂). - The chromium in K₂Cr₂O₇ will be reduced from +6 oxidation state to +3 oxidation state. 4. **Write the Half-Reactions**: - **Oxidation Half-Reaction**: \[ 2 I^- \rightarrow I_2 + 2 e^- \] - **Reduction Half-Reaction**: \[ Cr_2O_7^{2-} + 14 H^+ + 6 e^- \rightarrow 2 Cr^{3+} + 7 H_2O \] 5. **Balance the Overall Reaction**: To balance the overall reaction, we need to ensure that the number of electrons lost in the oxidation half-reaction equals the number of electrons gained in the reduction half-reaction. - Multiply the oxidation half-reaction by 3: \[ 6 I^- \rightarrow 3 I_2 + 6 e^- \] - Combine the balanced half-reactions: \[ Cr_2O_7^{2-} + 6 I^- + 14 H^+ \rightarrow 2 Cr^{3+} + 3 I_2 + 7 H_2O \] 6. **Identify the Oxidized Product**: From the balanced reaction, we can see that the iodide ions (I⁻) are oxidized to iodine (I₂). Therefore, the oxidized product is: \[ \text{I}_2 \] ### Final Answer: The oxidized product is **I₂** (iodine).
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AAKASH INSTITUTE- ALCOHOLS, PHENOLS AND ETHERS-Assignment Section -D (Assertion - reason type question)
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