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A: Ce^(+4) is a good oxidizing agent. R:...

A: `Ce^(+4)` is a good oxidizing agent.
R: `Sm^(+2)` is a good reducing agent

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion, then mark (1)

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion, then mark (2)

C

If Assertion is true statement but Reason is false, then mark (3)

D

If both Assertion and Reason are false statements, then mark (4)

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the given statements regarding cerium and samarium, we can break down the reasoning step by step. ### Step 1: Understand the Assertion The assertion states that `Ce^(+4)` is a good oxidizing agent. - **Explanation**: In the case of cerium, its most stable oxidation state is +4. This means that cerium in the +4 oxidation state has a tendency to gain electrons to revert to a lower oxidation state, which is +3. The ability to gain electrons indicates that it can oxidize other substances while itself being reduced. Therefore, cerium in the +4 state acts as a good oxidizing agent. ### Step 2: Understand the Reason The reason states that `Sm^(+2)` is a good reducing agent. - **Explanation**: For samarium, its maximum oxidation state is +3. When samarium is in the +2 oxidation state, it has the tendency to lose an electron to reach the +3 state. This process of losing electrons is characteristic of a reducing agent, as it reduces another substance by donating electrons. Hence, samarium in the +2 state is indeed a good reducing agent. ### Conclusion Both the assertion and the reason are correct. Therefore, the correct answer is that both statements are true. ### Final Answer - **Assertion (A)**: `Ce^(+4)` is a good oxidizing agent. (True) - **Reason (R)**: `Sm^(+2)` is a good reducing agent. (True)
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AAKASH INSTITUTE- ALCOHOLS, PHENOLS AND ETHERS-Assignment Section -D (Assertion - reason type question)
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  4. A : When 3,3-dimethyl butan - 2 - ol is heated in presence of concentr...

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  5. A : In esterification reaction , HCOOH is the most reactive acid among...

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  6. A : Ethers can't be distilled upto dryness due to fear of explosion . ...

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  7. A : Phenol does not react with NaHCO(3) . R : Phenol is less acid...

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  8. A : CH(3) - underset(O)underset(||)(C)-COOH gives haloform reaction ...

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  9. A : Diphenyl ether is prepared by Williamson synthesis . R : This...

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  10. A : Grignard's reagent is prepared in the presence of ether . R :...

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  11. A : CH(3) - underset(CH(3))underset(|)overset(CH(3))overset(|)(C)-CH=...

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  12. A : Two moles of Grignard reagent is consumed in the formation of ter...

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  13. A : CH(3)-underset(CH(3))underset(|)overset(CH(3))overset(|)(C)-O-CH...

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  14. A : Ortho - cresol is weaker acidic than meta-cresol . R : It is d...

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  15. A : Among all ortho halophenol , fluorophenol is least acidic . R ...

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  16. A : In esterification reaction alcohol act as nucleophile . R : ...

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  17. A : Phenol is manufactured by Dow 's pocess. R : It involves the ...

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  18. A : Primary alcohol is prepared by the reaction of primary amine with ...

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  19. A : Thte reactivity order of alcohols is 1^(@) gt 2^(@) gt 3^(@) for...

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  20. A : The dehydration of ethyl alcohol in presence of Al(2)O(2) at 633 ...

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